7066-13-9

Basic information

• Product Name: 1-Naphthalenecarbonitrile,2-amino-(9CI)
• Synonyms: 1-Naphthalenecarbonitrile,2-amino-(9CI);2-amino-1-naphthonitrile
• CAS NO: 7066-13-9
• Molecular Formula: C₁₁H₈N₂
• Molecular Weight: 168.19462
• Product Categories: BIPHENYL
• Mol File: 7066-13-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 388.2°Cat760mmHg
• Flash Point: 188.6°C
• Appearance: /
• Density: 1.22g/cm³
• Vapor Pressure: 3.12E-06mmHg at 25°C
• Refractive Index: 1.687
• CAS DataBase Reference: 1-Naphthalenecarbonitrile,2-amino-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Naphthalenecarbonitrile,2-amino-(9CI)(7066-13-9)
• EPA Substance Registry System: 1-Naphthalenecarbonitrile,2-amino-(9CI)(7066-13-9)

Safety Data

• Hazardous Substances Data: 7066-13-9(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 31, p. 2607, 1966 DOI: 10.1021/jo01346a035

InChI:InChI=1/C11H8N2/c12-7-10-9-4-2-1-3-8(9)5-6-11(10)13/h1-6H,13H2

Upstream product

• 79894-39-6 2-ethoxycarbonylaminonaphthalene-1-carbonitrile 
• 20937-86-4 2-azidonaphthalene 
• 151-50-8 potassium cyanide 

Downstream Products

• 101874-56-0 2-benzylidenamino-[1]naphthonitrile 
• 60709-00-4 1-phenyl-4H-benzo[f]quinazolin-3-one 
• 109297-28-1 2-Chloronaphthalene-1-carbonitrile 
• 91-59-8 naphthalen-2-ylamine 
• 78584-83-5 2-benzyl-1,3-dioxo-1,2,3,4-tetrahydrobenzoquinazoline 
• 78584-82-4 2-cyclohexyl-1,3-dioxo-1,2,3,4-tetrahydrobenzoquinazoline 
• 79894-44-3 pyridinium salt of 1,1-dicyano-2-hydroxy-2-(N-benzoyl-1-cyano-2-naphthylamino)ethylene 
• 79894-48-7 2-phenyl-1,3-dioxo-1,2,3,4-tetrahydrobenzoquinazoline 
• 79894-45-4 2-benzoylaminonaphthalene-1-carbonitrile 
• 6329-24-4 2-acetoaminonaphthalene-1-carbonitrile 
• 154848-96-1 2--1-benzoylnaphthalene 
• 82833-07-6 N-(1-Cyano-naphthalen-2-yl)-4-nitro-benzamide 
• 116400-82-9 2-amino-1-benzoylnaphthalene 
• 82833-08-7 N-(1-Cyano-naphthalen-2-yl)-2-oxo-2-phenyl-acetamide 

Relevant articles and documents

PHOTOCHEMICAL DECOMPOSITION OF 2-AZIDOPHENAZINE IN ALCOHOLS AND IN THE PRESENCE OF CYANIDE ION

The photochemical decomposition of 2-azidophenazine in alcoholic solvents has been investigated. 1-Amino-2-alkoxyphenazines are formed in neutral and (in higher yield and together with 2-amino-1-chlorophenazine) in acidic conditions, while the azepinoquinoxaline 7 is formed in basic conditions.With cyanide ion nucleophilic attack takes place giving 1-amino-2-phenazine carbonitrile.To allow comparison, 2-azidonaphthalene, 2-azidoanthracene and 2-azidoanthraquinone have also been photodecomposed in the conditions in which the most interesting results are obtained from 2-azidophenazine.The mechanism of these reactions is briefly discussed.