70766-02-8

Basic information

• Product Name: N-(9H-fluoren-9-ylidene)-1-phenylmethanamine
• Synonyms: N-(9H-fluoren-9-ylidene)-1-phenylmethanamine
• CAS NO: 70766-02-8
• Molecular Weight: 269.346
• Mol File: 70766-02-8.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: N-(9H-fluoren-9-ylidene)-1-phenylmethanamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(9H-fluoren-9-ylidene)-1-phenylmethanamine(70766-02-8)
• EPA Substance Registry System: N-(9H-fluoren-9-ylidene)-1-phenylmethanamine(70766-02-8)

Safety Data

• Hazardous Substances Data: 70766-02-8(Hazardous Substances Data)

Upstream product

• 81532-35-6 benzaldehyde 9-fluorenyl imine 
• 73311-38-3 C₂₀H₁₅NO 
• 486-25-9 9-fluorenone 
• 100-46-9 benzylamine 
• 60048-18-2 fluoreneone imine hydrochloride 
• 81532-40-3 N-Benzyl-N-(9H-fluoren-9-yl)-4-methyl-benzenesulfonamide 
• 81532-38-9 9-(N-Benzylamino)fluorene 
• 6630-65-5 9-chlorofluorene 

Downstream Products

• 73311-38-3 C₂₀H₁₅NO 
• 70766-00-6 2'-benzyl-4'-tert-butyl-5'-oxo-spiro[fluorene-9,3'-isoxazolidine]-4'-carbonitrile 
• 622-29-7 N-Benzylidenemethylamine 
• 100-52-7 benzaldehyde 
• 92-29-5 (E,E)-1,3,5-triphenyl-2,4-diazapenta-1,4-diene 
• 16118-22-2 benzylidenamine 
• 486-25-9 9-fluorenone 
• 3400-12-2 2-methyl-3-phenyl-oxaziridine 
• 7471-95-6 9H-fluorene-9-carboxamide 
• 70765-97-8 N-Benzyl α,α-(diphenyl-2,2'-diyl)nitrone 

Relevant articles and documents

Scandium(III) Triflate Catalyzed Direct Synthesis of N-Unprotected Ketimines

N-Unprotected ketimines are useful substrates and intermediates for synthesizing valuable nitrogen-containing compounds, but their potential applicability is limited by the available synthetic methods. To address this issue, we report a scandium(III) triflate catalyzed direct synthesis of N-unprotected ketimines. Using commercially available reagents and Lewis acid catalysts, ketones were directly transformed into the corresponding N-unprotected ketimines in high yields with broad functional group tolerance, even in multigram scales. The reactions were readily applicable for one-pot synthesis of important compounds such as a glycine Schiff base without isolation of N-unprotected ketimine intermediates. Preliminary mechanistic studies to clarify the reaction mechanism are also described.

X=Y-ZH SYSTEMS AS POTENTIAL 1,3-DIPOLES. PART 21 ACTIVATION OF THE ZH PROTON IN IMINES.

Imines, RCH=N-ZH, possessing a range of ZH groups (Z=CHCOPh, CHCOSR, CHCONHR, CHP(O)(OEt)2, 2-CH-pyridyl, 2-CH-thiazolyl, and 9-fluorenyl) undergo thermal 1,2-prototropy generating azomethine ylides stereospecifically.The intermediate azomethine ylides un

The Synthesis of NH Aldimines and Derivatives by Spontaneous and Base-catalysed Decomposition of Oxaziridines

A range of oxaziridines containing N-methylene substituents has been synthesized by peracid oxidation of the corresponding fluorenylidene N-alkylamines.Spontaneous and tertiary amine base-catalysed decomposition of the oxaziridines into unstable NH aldimines and derivatives was observed.Acrylaldehyde, 2-methylacrylaldehyde, and benzaldehyde NH imines have been identified as initial products from decomposition of the corresponding oxaziridines. 2,4,6-Trialkylhexahydro-1,3,5-triazines, N,N'-dialkylidene-1,1-diaminoalkanes, N,N'-diarylidene-1,1-diaminoalkanes, and N-isobutylidene-2-methylpropenylamine were among the isolated products formed via the undetected alkyl aldehyde NH imines resulting from oxaziridine decomposition.