70848-22-5Relevant academic research and scientific papers
Synthesis of mono-, di-, and triaminobismuthanes and observation of C-C coupling of aromatic systems with bismuth(iii) chloride
Hering-Junghans, Christian,Schulz, Axel,Thomas, Max,Villinger, Alexander
, p. 6053 - 6059 (2016)
The reaction of lithium N-trimethylsilyl-amides of the type RN(SiMe3)Li with bismuth(iii) chloride yielded mono-, di- or triaminobismuthanes depending on the sterical demand of the anilide ligand R and the used stoichiometry. For the bulky Mes? substituent the reaction with BiCl3 resulted in the formation of a C-C coupling product as the main product besides a small amount of the expected Mes?N(SiMe3)BiCl2.
Reactions of 2,4,6-triisopropylaniline with phosphorus trihalides. Molecular structure of 1,3-di(2,4,6-triisopropylphenyl)-2,4-dichloro-1,3,2,4-diazadiphoshetidine
Romanenko, V.D.,Drapailo, A.B.,Chernega, A.N.,Markovskii, L.N.
, p. 2260 - 2266 (2007/10/02)
2,4,6-Triisopropylaniline reacts with PCl3 (1:1) in the presence of triethylamine to form 1,3-di(2,4,6-triisopropylphenyl)-2,4-dichloro-1,3,2,4-diazadiphosphetidine.Analogous products are obtained through reaction of ArN(Li)SiMe3 (Ar=2,4,6-i-Pr3C6H2) with
