7086-80-8

Basic information

• Product Name: 2-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohexanone
• CAS NO: 7086-80-8
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.2328
• Mol File: 7086-80-8.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 269.3°C at 760 mmHg
• Flash Point: 112.2°C
• Density: 1.026g/cm³
• Vapor Pressure: 0.000975mmHg at 25°C
• Refractive Index: 1.489
• CAS DataBase Reference: 2-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohexanone(7086-80-8)
• EPA Substance Registry System: 2-hydroxy-2-methyl-5-(prop-1-en-2-yl)cyclohexanone(7086-80-8)

Safety Data

• Hazardous Substances Data: 7086-80-8(Hazardous Substances Data)

Upstream product

• 124-41-4 sodium methylate 
• 506422-90-8 2-bromo-1-hydroxy-p-menth-8-ene 
• 59121-82-3 (1R,2R,4S)-1-methyl-4-(prop-1-en-2-yl)cyclohexane-1,2-diol 
• 203719-53-3 (-)-limonene oxide 
• 39904-04-6 (1S,2S,4S)-limonene glycol 
• 1946-00-5 (1S,2S,4R)-limonene-1,2-diol 
• 5989-27-5 D-limonene 
• 1195-92-2 Limonene oxide 
• 13833-08-4 1-methyl-4-(1-methylethenyl)-cyclohexane-1,2-diol 
• 6485-40-1 (R)-Carvone 
• 185329-56-0 1-methyl-4-(1-methylethenyl)-1,2-cyclohexanediol 
• 39904-09-1 (1R,2R,4R)-1-methyl-4-(prop-1-en-2-yl)cyclohexane-1,2-diol 

Downstream Products

• 7105-59-1 methyl (3R)-3-isopropenyl-6-oxoheptanoate 

Relevant articles and documents

Microwave assisted bi-functional activation of β-bromo-tert-alcohols

Microwave-assisted dehydration-oxidation of β-bromo-tert-alcohols to afford 2,3-unsaturated ketones in good yield is reported. The reaction of substrates with DMSO in 1:1 ratio (w/v) is promoted by ZnS in a solvent-free condition. A concurrent bi-functional activation of trans-vicinal bromo- and hydroxyl groups with ZnS is elucidated. This is a new observation under microwave and applies to β-bromo-tert-alcohols derived from 1,4-disubstitued-1-cyclohexenes. It is very useful in the synthesis of 2,3-unsaturated ketones derived from monoterpenes which are valuable flavour compounds. [Figure not available: see fulltext.]

Synthesis of the proposed structures of Prevezol C

The first enantioselective synthesis of the proposed relative structures of Prevezol C is reported in 11 linear steps from readily available materials. The unusual syn bromohydrin was installed via a multistep sequence culminating in a diastereoselective

A new diastereoselective entry to the (1S,4R)- and (1S,4S)-isomers of 4-isopropyl-1-methyl-2-cyclohexen-1-ol, aggregation pheromones of the ambrosia beetle Platypus quercivorus

A concise diastereoselective and enantiopure route to the (1S,4R)- and (1S, 4S)-isomers of 4-isopropyl-1-methyl-2-cyclohexen-1-ol via a palladium-catalysed deoxygenation of the enol triflate derived from limonene glycol. Crown Copyright