7087-77-6

Basic information

• Product Name: 1,3-Propanediol, 2-methyl-1-phenyl-, (1R,2R)-rel-
• CAS NO: 7087-77-6
• Molecular Formula: C10H14O2
• Molecular Weight: 166.22
• Mol File: 7087-77-6.mol
• Article Data: 53

Chemical Properties

• CAS DataBase Reference: 1,3-Propanediol, 2-methyl-1-phenyl-, (1R,2R)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Propanediol, 2-methyl-1-phenyl-, (1R,2R)-rel-(7087-77-6)
• EPA Substance Registry System: 1,3-Propanediol, 2-methyl-1-phenyl-, (1R,2R)-rel-(7087-77-6)

Safety Data

• Hazardous Substances Data: 7087-77-6(Hazardous Substances Data)

Upstream product

• 25201-44-9 (1S,2S)-2-methyl-1-phenyl-3-buten-1-ol 
• 139017-19-9 (3R,4R)-3-Methyl-4-phenyl-1-oxa-5-sila-spiro[4.5]decane 
• 205692-08-6 (2R,3S)-3-Hydroxy-2-methyl-3-phenyl-propionic acid (1R,2S)-2-[methyl-(1,2,3,4,5,6,7,8-octahydro-anthracene-9-sulfonyl)-amino]-1-phenyl-propyl ester 
• 100-52-7 benzaldehyde 
• 123-38-6 propionaldehyde 
• 205692-07-5 (2R,3R)-3-Hydroxy-2-methyl-3-phenyl-propionic acid (1R,2S)-2-[methyl-(1,2,3,4,5,6,7,8-octahydro-anthracene-9-sulfonyl)-amino]-1-phenyl-propyl ester 
• 116047-21-3 3-((tert-butyl)dimethylsiloxy)-2-methyl-1-phenylpropan-1-one 
• 17226-81-2 ethyl (2R*,3R*)-3-hydroxy-2-methyl-3-phenylpropanoate 
• 16735-22-1 3-hydroxy-2-methylpropiophenone 
• 16735-22-1 (S)-3-hydroxy-2-methyl-1-phenylpropan-1-one 
• 1631-83-0 diphenylsilyl chloride 
• 363609-34-1 (2R,3R)-3-Hydroxy-2-methyl-3,N-diphenyl-propionamide 
• 902451-78-9 (S)-3-(4-methoxybenzyloxy)-2-methyl-1-phenylpropan-1-one 
• 157197-98-3 (4S,5S)-1,3-di(3-phenyl-3-hydroxy-2-methylpropionyl)-4,5-di(benzyloxymethyl)imidazolidin-2-one 

Downstream Products

• 22821-07-4 2-(butylthio)benzo[d]oxazole 
• 2382-96-9 2-sulfanyl-1,3-benzoxazole 
• 84784-81-6 erythro-2-methyl-3-phenyl-1,3-propanediol 1-methoxyethoxymethyl ether 

Relevant articles and documents

Confinement-Controlled, Eithersyn- oranti-Selective Catalytic Asymmetric Mukaiyama Aldolizations of Propionaldehyde Enolsilanes

Protected aldols (i.e., true aldols derived from aldehydes) with eithersyn- oranti- stereochemistry are versatile intermediates in many oligopropionate syntheses. Traditional stereoselective approaches to such aldols typically require several nonstrategic

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SN2 Reactions at Tertiary Carbon Centers in Epoxides

Described herein is a novel concept for SN2 reactions at tertiary carbon centers in epoxides without activation of the leaving group. Quantum chemical calculations show why SN2 reactions at tertiary carbon centers are proceeding in these systems. The reaction allows flexible synthesis of 1,3-diol building blocks for natural product synthesis with excellent control of the relative and absolute configurations.