22336-76-1

Basic information

• Product Name: Bicyclo[2.2.1]heptan-2-ol, 4,7,7-trimethyl-
• CAS NO: 22336-76-1
• Molecular Formula: C10H18O
• Molecular Weight: 154.252
• Mol File: 22336-76-1.mol

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]heptan-2-ol, 4,7,7-trimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptan-2-ol, 4,7,7-trimethyl-(22336-76-1)
• EPA Substance Registry System: Bicyclo[2.2.1]heptan-2-ol, 4,7,7-trimethyl-(22336-76-1)

Safety Data

• Hazardous Substances Data: 22336-76-1(Hazardous Substances Data)

Upstream product

• 464-17-5 1,7,7-trimethylbicyclo[2.2.1]hept-2-ene 
• 7722-84-1 dihydrogen peroxide 
• 64-19-7 acetic acid 
• 53702-18-4 (+/-)-epicamphor 

Downstream Products

• 70897-07-3 4,7,7-Trimethyl-bicyclo[2.2.1]heptan-2-one 
• 6053-45-8 2,2-dimethyl-cyclopentane-1,1,3-tricarboxylic acid 
• 2767-84-2 Camphorquinone 
• 20279-54-3 benzoic acid epibornyl ester 

Relevant articles and documents

A SUBSTITUTED CINNAMOYL ESTER FROM CLEISTOPHOLIS STAUDTII

Cleistophostaudin, the novel ester, 3-hydroxy-1,7,7-trimethyl bicycloheptanyl-(trans)-4-hydroxy-3-methoxycinnamate was isolated from the stem bark of Cleistopholis staudtii, and its structure determined by spectroscopic data and degradative studies.The previously known methyl-(trans)-(trans)-10,11-dihydroxyfarnesoate was also isolated from the same source.

A mild and efficient flow procedure for the transfer hydrogenation of ketones and aldehydes using hydrous zirconia

A flow chemistry Meerwein-Ponndorf-Verley (MPV) reduction procedure using partially hydrated zirconium oxide via a machine-assisted approach is reported. The heterogeneous reductive system could be applied to a wide range of functionalized substrates, allowing clean and fast delivery of the alcohol products within a few minutes (6-75 min). In three examples the system was scaled to deliver 50 mmol of product.

A NEW COMBINED OXIDIZING REAGENT SYSTEM, Fe(CH3CN)6(3+)-IO4(1-): OXIDATION OF PARAFFIN HYDROCARBONS

Combined oxidizing reagent systems of Fe(AN)6ClO4)3 ( AN = acetonitrile ) with halogen oxyacids were investigated.In particular, reactions of paraffin hydrocarbons with a combined reagent system of Fe(AN)6(3+) were explored because of the high reactivity of this system in the oxidation of adamantane ( Table 1 ).Oxidation of bornane, norbornane, cyclohexane, and n-hexane gave the corresponding acetamides and acetates ( Tabla II ).These results shows that the title reagent system can efficiently oxidize organic substrates which have onset potentials of anodic current of ca. 2.7 V vs. saturated calomel electrode.Keywords - oxidation; paraffin hydrocarbon; combined reagent system; hexakisacetonitrile iron(III) perchlorate; halogen oxyacid; sodium periodate