70962-62-8Relevant academic research and scientific papers
A PROCESS FOR THE PREPARATION OF PYRYLIUM SALTS
-
Page/Page column 17, (2019/08/29)
The present invention relates to the process for the preparation of Pyrylium salts having the formula represented below. Present invention provide a simplified method of producing symmetrical and unsymmetrical pyrylium salts. The invention explores readily available starting materials with reaction conditions which are suitable for industrial scale applications. All the synthesized compounds were confirmed by various spectroscopic techniques such as Fourier transform infrared spectroscopy, 1H NMR, 13C NMR, 19F NMR spectroscopy, and single-crystal X-ray analysis. Mass of the compounds confirmed by HRMS analysis.
Synthesis of symmetrical and unsymmetrical triarylpyrylium ions: Via an inverse electron demand Diels-Alder reaction
Fathimath Salfeena,Basavaraja,Ashitha,Kumar, V. Praveen,Varughese, Sunil,Suresh, Cherumuttathu H.,Sasidhar
, p. 12463 - 12466 (2018/11/20)
BF3·OEt2 mediated inverse electron demand Diels-Alder (IEDDA) reaction of chalcones with aryl acetylenes is reported for the synthesis of symmetrical and unsymmetrical 2,4,6-triarylpyrylium ions. The protocol provides an effective one-pot method for the utilization of readily available simple substrates under mild reaction conditions leading to a diverse array of pyrylium ions in moderately good yield.
Synthesis of pyrylium salts by the action of the trityl cation on penta-2,4-dienones. Experimental study and mechanism
Barry-Kone, N.,Fossey, J.,Loupy, A.,Sib, S. F.,Simalty, M.,Sorba, J.
, p. 218 - 222 (2007/10/02)
The mechanism of the formation of pyrylium perchlorate or triflate salts has been investigated by reacting the trityl cation with several penta-2,4-dienones.The influence of various structural factors and the nature of the electrophilic reactant was studi
The Preparation of 2,4,6-Triphenylpyrylium Trifluoromethanesulphonate, Fluorosulphonate, Ethoxysulphonate, Naphthalene-2-sulphonate, Stannochloride, Trichloroacetate, and Trifluoroacetate and other Pyrylium Trifluoromethanesulphonates and their Reactions
Katritzky, Alan R.,El-Mowafy, Azzahra M.,Marzorati, Liliana,Patel, Ranjan C.,Thind, Sukhpal S.
, p. 4001 - 4030 (2007/10/02)
The title pyrylium salts are all readily prepared in high yield from 1,3,5-triphenylpent-2-ene-1,5-dione.Amines react with the trifluoromethanesulphonate, naphthalene-2-sulphonate, and trifluoroacetate to give the corresponding pyridinium salts in high yi
