709674-10-2Relevant academic research and scientific papers
Stereochemistry of the tetrabutylammonium cyanide-catalyzed cyanosylilation of cyclic α,β-epoxyketones - Dependence of the diastereoselectivity on the ring size
Aljarilla, Ana,Cordoba, Ruben,Csaky, Aurelio G.,Fernandez, Israel,Ortiz, Fernando Lopez,Plumet, Joaquin,Gomez, Gloria Ruiz
, p. 3969 - 3976 (2007/10/03)
The diastereoselective Bu4NCN-catalyzed addition of TMSCN to cyclic α,β-epoxyketones has been considered. Good diastereoselectivities were found, depending on the ring size of the starting material. Computational studies account for the observed diastereoselectivities. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
