709674-12-4

Basic information

• Product Name: 6-Oxabicyclo[3.1.0]hexane-2-carbonitrile,2-[(trimethylsilyl)oxy]-,(1R,2S,5S)-rel-(9CI)
• Synonyms: 6-Oxabicyclo[3.1.0]hexane-2-carbonitrile,2-[(trimethylsilyl)oxy]-,(1R,2S,5S)-rel-(9CI)
• CAS NO: 709674-12-4
• Molecular Formula: C9H15NO2Si
• Molecular Weight: 197.3064
• Product Categories: CYCLOPENTANE
• Mol File: 709674-12-4.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 6-Oxabicyclo[3.1.0]hexane-2-carbonitrile,2-[(trimethylsilyl)oxy]-,(1R,2S,5S)-rel-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Oxabicyclo[3.1.0]hexane-2-carbonitrile,2-[(trimethylsilyl)oxy]-,(1R,2S,5S)-rel-(9CI)(709674-12-4)
• EPA Substance Registry System: 6-Oxabicyclo[3.1.0]hexane-2-carbonitrile,2-[(trimethylsilyl)oxy]-,(1R,2S,5S)-rel-(9CI)(709674-12-4)

Safety Data

• Hazardous Substances Data: 709674-12-4(Hazardous Substances Data)

Upstream product

• 930-30-3 cyclopent-2-enone 
• 130249-17-1 2,3-epoxycyclopentanone 
• 7677-24-9 trimethylsilyl cyanide 

Relevant articles and documents

Stereochemistry of the tetrabutylammonium cyanide-catalyzed cyanosylilation of cyclic α,β-epoxyketones - Dependence of the diastereoselectivity on the ring size

The diastereoselective Bu4NCN-catalyzed addition of TMSCN to cyclic α,β-epoxyketones has been considered. Good diastereoselectivities were found, depending on the ring size of the starting material. Computational studies account for the observed diastereoselectivities. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.