71052-62-5

Upstream product

• 71052-61-4 (1R)-1-[1-(2,4-dinitro-phenyl)-1H-pyrazol-3-yl]-O²,O³;O⁴,O⁵-diisopropylidene-O¹-methanesulfonyl-D-arabinitol 
• 75155-97-4 (2R,3R,4S)-1,3,4-Tris-benzyloxy-8,8-diethoxy-oct-6-yne-2,5-diol 
• 75155-98-5 1,1-diethoxy-3-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)prop-2-yne 
• 59967-95-2 3(5)-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)pyrazole 
• 65101-21-5 tri-O-benzyl-aldehydo-D-allo-4,7-anhydro-2,3-dideoxy-oct-2-ynose 
• 70-34-8 2,4-Dinitrofluorobenzene 
• 16838-89-4 2,3,5-tri-O-benzyl-D-ribofuranose 
• 75155-99-6 1-(2,4-dinitrophenyl)-3-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)pyrazole 
• 71052-58-9 (1R)-O²,O³;O⁴,O⁵-diisopropylidene-1-(1⁽²⁾H-pyrazol-3-yl)-D-arabinitol 

Downstream Products

• 75156-00-2 1-(2,4-dinitrophenyl)-3-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)pyrazole 
• 75173-95-4 1-(2,4-dinitrophenyl)-3-(2,3,5-tri-O-acetyl-β-D-ribofuranosyl)-4-nitropyrazole 

Relevant academic research and scientific papers

C-Nucleoside Studies. Part 10. A New Synthesis of 3-(2,3,5-Tri-O-benzyl-β-D-ribofuranosyl)pyrazole and its Conversion into 4-Nitro-3(5)-β-D-ribofuranosylpyrazole

1,1-Diethoxy-3-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)prop-2-yne (12) has been synthesised from 2,3,5-tri-O-benzyl-D-ribofuranose in 52percent yield.Acidic hydrolysis followed by reaction with hydrazine affords 3-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)pyraz

A New Synthesis of Formycin via Nitropyrazole Derivatives

3-(2,3,5-Tri-O-benzyl-β-D-ribofuranosyl)pyrazole (4) has been converted into formycin (15) by a sequence involving, as the key step, cine substitution, by cyanide ion, of the 1-nitro group in the 1,4-dinitro-pyrazole (10).