75173-95-4Relevant academic research and scientific papers
C-Nucleoside Studies. Part 10. A New Synthesis of 3-(2,3,5-Tri-O-benzyl-β-D-ribofuranosyl)pyrazole and its Conversion into 4-Nitro-3(5)-β-D-ribofuranosylpyrazole
Buchanan, J. Grant,Edgar, Alan R.,Hutchison, Roderick J.,Stobie, Alan,Wightman, Richard H.
, p. 2567 - 2571 (2007/10/02)
1,1-Diethoxy-3-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)prop-2-yne (12) has been synthesised from 2,3,5-tri-O-benzyl-D-ribofuranose in 52percent yield.Acidic hydrolysis followed by reaction with hydrazine affords 3-(2,3,5-tri-O-benzyl-β-D-ribofuranosyl)pyraz
A New Synthesis of Formycin via Nitropyrazole Derivatives
Buchanan, J. Grant,Edgar, Alan R.,Hutchison, Roderick J.,Stobie, Alan,Wightman, Richard H.
, p. 237 - 238 (2007/10/02)
3-(2,3,5-Tri-O-benzyl-β-D-ribofuranosyl)pyrazole (4) has been converted into formycin (15) by a sequence involving, as the key step, cine substitution, by cyanide ion, of the 1-nitro group in the 1,4-dinitro-pyrazole (10).
