7116-86-1Relevant articles and documents
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Glaze,W.H. et al.
, p. 233 - 240 (1973)
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Assembly and disassembly of Langmuir-Blodgett films on poly[1- (trimethylsilyl)-1-propyne]: The uniqueness of calix[6]arene multilayers as permeation-selective membranes
Hendel, Robert A.,Nomura, Eisaku,Janout, Vaclav,Regen, Steven L.
, p. 6909 - 6918 (2007/10/03)
A series of calix[6]arene-based surfactants have been synthesized, which contain amide oxime head groups on their upper rim and 5,5-dimethylhexyl (I), n-octyl (II), n-dodecyl (III), and n-hexadecyl (IV) groups on their lower rim. Composite membranes that were fabricated from Langmuir-Blodgett (LB) multilayers derived from each surfactant plus poly[1-(trimethylsilyl)-1- propyne] (PTMSP) cast film showed a significant increase in their selectivity toward helium and nitrogen, relative to bare PTMSP. In sharp contrast, analogous composites that were prepared with LB multilayers of conventional single chain surfactants [arachidic acid (AA), cadmium arachidate (AA/Cd2+) and stearoamideoxime (SA)] exhibited permeation properties that were identical with those of bare PTMSP. When a polymeric surfactant [poly(1- octadecene-co-maleic anhydride), POM] is used for LB film construction, a modest increase in selectivity was observed. These findings, together with an analysis of representative composites by X-ray photoelectron spectroscopy, provide compelling evidence for the presence of intact, calix[6]arene-based LB assemblies on the surface of PTMSP; with the conventional single chain surfactants, however, disassembly and absorption into the bulk phase of the support is favored. The results of this study highlight the need for having individual surfactant molecules span individual pores on the surface of the support and strong intermolecular forces between neighboring surfactants to produce relatively defect-free LB films.
Mechanism of Reaction of Geminal Dihalides with Lithium Naphthalenide (LiNp(.-)): Evidence for an Electron Transfer Mechanism. Similarities to the Mechanism of Reaction of Geminal Dihalides with Certain Nucleophiles and Other One-Electron Donors
Ashby, E. C.,Desphande, Abhay K.
, p. 4530 - 4535 (2007/10/02)
The reactions of the sterically hindered geminal dihalides 6,6-dichloro-5,5-dimethyl-1-hexene (1a) and 6,6-diiodo-5,5-dimethyl-1-hexene (1b) with lithium naphthalenide (LiNp(.-)) in THF were investigated in an attempt to compare the results of reactions involving a known one-electron donor (LiNp(.-)) with those involving nucleophiles believed to be one-electron donors.On the basis of radical-trapping studies, deuterium tracer studies, and product studies using cyclizable radical probes, it can be concluded that the reactions studied are very similar to those reported by us earlier involving magnesium metal, LiAlH4, and other nucleophiles.In addition to radical-derived products, the reaction of 1a with LiNp(.-) afforded hydrocarbons, in high yields, that were derived from a carbene intermediate.On the other hand, 1b, on reaction with LiNp(.-), did not yield any carbene-derived hydrocarbons.These results show that the formation of a carbene intermediate, derived from a radical, depends on the nature of the halogen present.It was also found that naphthalene can behave as a hydrogen atom donor toward a radical in the presence of known hydrogen atom donors, such as THF.