71189-76-9Relevant academic research and scientific papers
Stereoselective formation of bis(α-hydroxy ketones) via enzymatic carboligation
Duennwald,Mueller
, p. 8608 - 8612 (2000)
The enzymatic approach to a novel class of chiral bis(α-hydroxy ketones) of type 5 and 8, which enable the synthesis of new multidentate ligands for asymmetric transition metal catalysis, is described. The key step is the second benzoylformate decarboxyla
n-Butyllithium as a highly efficient precatalyst for cyanosilylation of aldehydes and ketones
Kang, Zihan,Wang, Yuhong,Xu, Xiaojuan,Xue, Mingqiang,Zhang, Wenxuan,Zhou, Shuai,Zhu, Xu
supporting information, p. 7432 - 7437 (2021/09/07)
A highly efficient cyanosilylation protocol mediated by the easily availablen-BuLi with a wide range of aldehydes and ketones was developed. This protocol features excellent yields with very lown-BuLi loadings (0.01-0.05 mol%) at room temperature, solvent
Solvent-Induced Facile Synthesis of Cubic-, Spherical-, and Honeycomb-Shape Palladium N-Heterocyclic Carbene Particles and Catalytic Applications in Cyanosilylation
Zhao, Huaixia,Li, Xinxiong,Li, Liuyi,Wang, Ruihu
, p. 3642 - 3647 (2015/08/18)
The facile synthesis of palladium N-heterocyclic carbene (NHC) particles with spherical, cubic, and honeycomb morphologies is accomplished. The structures of cubic and honeycomb particles are defined as an unprecedented trinuclear palladium-NHC complex. A
Structural aspects of nucleation inhibitors for diastereomeric resolutions and the relationship to Dutch resolution
Leeman, Michel,Brasile, Giuseppina,Gelens, Edith,Vries, Ton,Kaptein, Bernard,Kellogg, Richard
, p. 1287 - 1290 (2008/12/22)
You say you want a resolution: Nucleation inhibitors for the resolution of diastereomers by selective crystallization have been designed and tested. The resolution of racemic 3-methoxyphenylethylamine was optimized with (S)-mandelic acid as the resolving agent (see scheme). Multifunctional inhibitors are particularly effective. (Chemical Equation Presented).
