712-32-3Relevant academic research and scientific papers
Nitration of deactivated aromatic compounds via mechanochemical reaction
Wu, Jian-Wei,Zhang, Pu,Guo, Zhi-Xin
supporting information, (2021/05/05)
A variety of deactivated arenes were nitrated to their corresponding nitro derivatives in excellent yields under high-speed ball milling condition using Fe(NO3)3·9H2O/P2O5 as nitrating reagent. A radical involved mechanism was proposed for this facial, eco-friendly, safe, and effective nitration reaction.
Towards the development of non-enediyne approaches for mimicking enediyne chemistry: Design, synthesis and activity of a 1,4-bisdiazonium compound
Arya, Dev P.,Jebaratnam, David J.
, p. 4369 - 4372 (2007/10/02)
1,4-bisdiazonium compounds, whichmay be precursors of aryl 1,4-diradicals, have the potential to mimic the DNA cleaving activity of the enediyne antibiotics. To this end, the ability to generate and activate 1,4-bisdiazonium compounds in good yield (e.g.,
Catalytic Autoxidation of Benzoquinone Dioximes with Nitrogen Oxides: Steric Effects on the Preparation of Monomeric Dinitrosobenzenes
Rathore, R.,Kim, J. S.,Kochi, J. K.
, p. 2675 - 2684 (2007/10/02)
A convenient catalytic method for the autoxidation of quinone dioximes to dinitrosobenzenes with dioxygen is based on the presence of small amounts of nitrogen oxides.The catalytic cycle is deduced from the facile chemical oxidation of quinone dioxime to dinitrobenzene with stoichiometric amounts of the 1-electron oxidant, nitrosonium-either as the NO+BF4- salt or the disproportionated ion pair NO+NO3- derived from nitrogen dioxide.The regeneration of NO+ occurs by the subsequent oxidation of nitric oxide (NO) with dioxygen to nitrogen dioxide followed by the disproportionation to nitrosonium nitrate in the presence of electron-rich donors.Indeed, dioximes of various p-benzoquinones are shown to be strong reducing agents by transient electrochemistry.Electrochemical oxidation also leads to dinitrosobenzenes in good yields at anodic potentials of ca. 1.3 V.The substitution of p-dinitrosobenzene with bulky alkyl groups stabilizes the monomeric form, which is otherwise extensively associated.
Reactions of 1,4-Dimethyl-4-nitro-cyclohexa-2,5-dien-1-yl Acetates with Nitrogen Dioxide; the Formation of Polynitro Cyclohexenyl Esters
Abell, Andrew D.,Hartshorn, Michael P.,Maclennan, Michael E.,Robinson, Ward T.,Wright, Graeme J.
, p. 43 - 51 (2007/10/02)
Reactions of the epimeric 4-nitrocyclohexa-2,5-dienyl acetates (10) and (11) with nitrogen dioxide in acetic anhydride give closely similar mixtures of the nitro aromatic compounds (12)-(15), three polynitro nitrate esters (16)-(18), and two polynitro acetates (19) and (20).X-Ray crystal structure determinations are reported for compounds (16)-(18).
