71208-20-3

Basic information

• Product Name: 1,2,3,4-tetra-O-acetyl-6-O-benzoyl-α-D-glucopyranose
• Synonyms: 1,2,3,4-tetra-O-acetyl-6-O-benzoyl-α-D-glucopyranose
• CAS NO: 71208-20-3
• Molecular Weight: 452.415
• Mol File: 71208-20-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,2,3,4-tetra-O-acetyl-6-O-benzoyl-α-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3,4-tetra-O-acetyl-6-O-benzoyl-α-D-glucopyranose(71208-20-3)
• EPA Substance Registry System: 1,2,3,4-tetra-O-acetyl-6-O-benzoyl-α-D-glucopyranose(71208-20-3)

Safety Data

• Hazardous Substances Data: 71208-20-3(Hazardous Substances Data)

Upstream product

• 98-88-4 benzoyl chloride 
• 13100-46-4 1,2,3,4-tetra-O-acetyl-β-D-glucopyranose 
• 65-85-0 benzoic acid 
• 13100-46-4 1,2,3,4-tetra-O-acetyl-α-D-glucopyranoside 
• 492-62-6 alpha-D-glucopyranose 
• 14200-76-1 O⁶-Benzoyl-D-glucose 
• 108-24-7 acetic anhydride 

Downstream Products

• 71208-19-0 2,3,4-tri-O-acetyl-6-O-benzoylglucosyl bromide 
• 55286-97-0 1,2,3,6-tetra-O-acetyl-α-D-glucopyranoside 
• 13100-46-4 1,2,3,4-tetra-O-acetyl-α-D-glucopyranoside 
• 180072-39-3 3,4-di-O-acetyl-6-O-benzoyl-D-glucal 
• 88037-30-3 methyl 2,3,4-tri-O-acetyl-6-O-benzoyl-β-D-glucopyranoside 

Relevant articles and documents

Diastereoselective Synthesis of Thioglycosides via Pd-Catalyzed Allylic Rearrangement

Stereoselective glycosylation is challenging in carbohydrate chemistry. Herein, stereoselective thioglycosylation of glycals via palladium-catalyzed allylic rearrangement yields various substituents on α-isomer thioglycosides. Two comprehensive series of aryl and benzyl thioglycosides were obtained via a combination of thiosulfates with glycals derived from glucose, arabinose, galactose, and rhamnose. Furthermore, diosgenyl α-l-rhamnoside and isoquercitrin achieved selectivity via stereospecific [2,3]-sigma rearrangements of α-sulfoxide-rhamnoside and α-sulfoxide-glucoside, respectively.