71333-94-3Relevant academic research and scientific papers
QUINOLIZIDINES. XXIII. AN ALTERNATIVE SYNTHETIC ROUTE TO BENZOQUINOLIZIDINE-TYPE ALANGIUM ALKALOIDS FROM ETHYL CINCHOLOIPONATE
Fujii, Tozo,Ohba, Masashi,Shimohata, Kaori,Yoshifuji, Shigeyuki
, p. 2949 - 2957 (2007/10/02)
The trans lactam acid (+)-XX was isolated in good yield in the form of the 4-methoxybenzyl ester (+)-XXV from an equilibrated 66:34 mixture of the trans and cis isomers , which was obtained by thermal cis-trans isomerization of the cis
Quinolizidines-V. A novel synthetic route to Ipecac alkaloids through chemical incorporation of ethyl cincholoiponate derived from the cinchona alkaloid cinchonine
Fujii, Tozo,Yoshifuji, Shigeyuki
, p. 1539 - 1545 (2007/10/02)
A new synthetic route to (-)-emetine (1) and related Ipecac alkaloids has been exploited in terms of the synthesis of the tricyclic ester (-)-30 from ethyl cincholoiponate [(+)-4], a degradation product of the Cinchona alkaloid cinchonine (7). The steps i
