71439-35-5

Upstream product

• 774-48-1 (diethoxymethyl)benzene 
• 27552-06-3 methyl 3-O-methyl-α-D-mannopyranoside 
• 4148-58-7 (4aR,6S,7S,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 52260-48-7 Methyl 4,6-O-benzylidene-3-O-methyl-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 14982-01-5 methyl 3-O-methyl-β-D-glucopyranoside 
• 100-44-7 benzyl chloride 
• 70144-57-9 methyl 4,6-O-benzylidene-3-O-methyl-β-D-glucopyranoside 

Downstream Products

• 187732-23-6 methyl 4-acetyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 461659-00-7 methyl 2,3,4,6-tetra(p-chlorobenzyl)-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 461658-99-1 methyl 2,3,4,6-tetrabenzyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 461658-85-5 methyl 2,3,4,6-tetra(p-chlorobenzyl)-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 461658-97-9 methyl 4-allyl-2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 461659-10-9 (2R,3R,4S,5S,6S)-3-Allyloxy-5-benzyloxy-2-benzyloxymethyl-4,6-dimethoxy-tetrahydro-pyran 
• 187732-24-7 methyl 2,6-dibenzyl-3-methyl-α-D-mannopyranosyl-(1->4)-2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 74426-45-2 2,3,4,6-tetra(p-chlorobenzyl)-α-D-mannopyranosyl-(1->1)-2,3,4,6-tetra(p-chlorobenzyl)-α-D-mannopyranoside 
• 187083-12-1 methyl 2,6-dibenzyl-3-methyl-α-D-mannopyranoside 
• 89177-18-4 methyl 2,4-di-O-benzyl-3-O-methyl-α-D-mannopyranoside 
• 128503-74-2 Methyl 2-O-benzyl-3-O-methyl-α-D-mannopyranoside 

Relevant academic research and scientific papers

Synthesis of methyl O-α-D-mannosyl-(1→4)-[(3-O-methyl-α-D-mannosyl) -(1→4)-]n3-O-methyl-α-D-mannosides (n = 0, 1, and 2) via dehydrative glycosylation

Methyl O-α-D-mannopyranosyl-(1→4)-[(3-O-methyl-α-D-mannopyranosyl -(1→4)-]n3-O-methyl-α-D-mannopyra-nosides (n = 0, 1, and 2), the lowest homologs related to the 3-O-methylmannose polysaccharides (MMP) from Mycobacterium smegmatis, were synthesized via dehydrative glycosylation reactions. The reagent systems, composed of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine, of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and 1, 8-diazabicyclo[5.4.0]undec-7-ene, and of trimethylsilyl trifuloromethanesulfonate and pyridine were useful.

Synthesis of a hexasaccharide acceptor corresponding to the reducing terminus of mycobacterial 3-O-methylmannose polysaccharide (MMP)

The title compound methyl O-(2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranosyl)-[( 1 → 4)-O-(2,6-di-O-benzyl-3-O-methyl-α-D-mannopyranosyl)]4-(1 → 4)-2,6-di-O-benzyl-3-O-methyl-α-D mannopyranoside (2) was synthesized in a blockwise manner, employin