74426-45-2Relevant academic research and scientific papers
Synthesis of methyl O-α-D-mannosyl-(1→4)-[(3-O-methyl-α-D-mannosyl) -(1→4)-]n3-O-methyl-α-D-mannosides (n = 0, 1, and 2) via dehydrative glycosylation
Hirooka, Motoko,Terayama, Megumi,Mitani, Emi,Koto, Shinkiti,Miura, Asako,Chiba, Kayo,Takabatake, Ayano,Tashiro, Takako
, p. 1301 - 1309 (2007/10/03)
Methyl O-α-D-mannopyranosyl-(1→4)-[(3-O-methyl-α-D-mannopyranosyl -(1→4)-]n3-O-methyl-α-D-mannopyra-nosides (n = 0, 1, and 2), the lowest homologs related to the 3-O-methylmannose polysaccharides (MMP) from Mycobacterium smegmatis, were synthesized via dehydrative glycosylation reactions. The reagent systems, composed of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine, of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and 1, 8-diazabicyclo[5.4.0]undec-7-ene, and of trimethylsilyl trifuloromethanesulfonate and pyridine were useful.
The Synthesis of α-D-Galactopyranosyl and α-D-Mannopyranosyl 2-Amino-2-deoxy-α-D-glucopyranosides and the Conformation of Their Glycoside Linkage
Koto, Shinkiti,Inada, Shigeru,Zen, Shonosuke
, p. 2728 - 2734 (2007/10/02)
A new analog of trehalosamine, α-D-galactopyranosyl 2-amino-2-deoxy-α-D-glucopyranoside, was synthesized by the glycosylation of 2,3,4,6-tetra-O-(p-chlorobenzyl)-α-D-galactopyranose with 3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranosyl
