7153-90-4Relevant academic research and scientific papers
Heteropoly acids as heterogeneous and reusable catalyst for α-thiocyanation of ketones
Chaskar, Atul C.,Yadav, Arun A.,Langi, Bhushan P.,Murugappan, Anita,Shah, Chetan
experimental part, p. 2850 - 2856 (2010/10/20)
Simple, efficient, and mild method for -thiocyanation of ketones in presence of heteropolyacid has been developed. This methodology offered -oxothiocyanates in good to excellent yields at room temperature in a highly selective manner. The catalyst could b
α-thiocyanation of carbonyl and β-dicarbonyl compounds using (dichloroiodo)benzene-lead(II) thiocyanate
Prakash,Kaur,Batra,Rani,Singh,Moriarty
, p. 2019 - 2023 (2007/10/03)
The combination reagent (dichloroiodo)benzene and lead(II) thiocyanate in dichloromethane effects oxidation of various enol silyl ethers, ketene silyl acetals, and β-dicarbonyl compounds, thereby providing an efficient and convenient method for α-thiocyanation of carbonyl and β-dicarbonyl compounds.
Pseudohalogen chemistry. XI. Some aspects of the chemistry of octhiocyanato-β-dicarbonyl compounds
Atkins, Elaine F.,Dabbs, Steven,Guy, Robert G.,Mahomed, Akbar A.,Mountford, Philip
, p. 7253 - 7264 (2007/10/02)
Enolised α-thiocyanato-β-dicarbonyl compounds dimerise in ethanol at room temperature to give tautomeric 4,5-disubstituted 2-amino- and 2-acetamido-thiazoles by a C-S-C + C-N cyclisation. Tautomerism is due to the unusual 4-(β-dicarbonyl-α-thio) substituent. Competing intramolecular cyclisations lead to minor amounts of heterocycles containing the thiazole and/or oxathiole ring systems.
