71564-36-8

Upstream product

• 201230-82-2 carbon monoxide 
• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 21475-90-1 cis-[Fe(CO)4Cl₂] 
• 1313-99-1 nickel(II) oxide 
• 13463-40-6 iron pentacarbonyl 
• 7732-18-5 water 
• 7440-02-0 nickel 
• 542-92-7 cyclopenta-1,3-diene 
• 13462-88-9 nickel dibromide 
• 83864-14-6 nickel dichloride 
• 13462-90-3 nickel(II) iodide 
• 57-13-6 urea 
• 13859-65-9 tetrakis(trifluorophosphine)nickel 

Downstream Products

• 91057-59-9 3-Carboxy-7-methyl-2,6-octadien-1-ol 
• 15484-46-5 methyl 2-hydroxymethylacrylate 
• 10080-68-9 (E)-ethyl 4-hydroxybut-2-enoate 
• 90113-57-8 2-Hydroxymethyl-acrylsaeure-isobutylester 
• 83864-14-6 nickel dichloride 
• 15747-45-2 (CO)2Ni(P(C₆H₅)(C₄H₉-n)2)2 
• 126506-26-1 (CO)3NiP(CF₃)2P(CF₃)2Ni(CO)3 
• 52729-09-6 (CO)3NiP(C₆H₄CH₃-p)3 
• 18716-80-8 tetracarbonylhydridoferrate 
• 13462-90-3 nickel(II) iodide 
• 201230-82-2 carbon monoxide 

Relevant academic research and scientific papers

Stable, three-coordinate Ni(CO)2(NHC) (NHC = N-heterocyclic carbene) complexes enabling the determination of Ni-NHC bond energies

The synthesis and characterization of three- and four-coordinate Ni(CO)n(NHC) (n = 2, 3; NHC = N-heterocyclic carbene) complexes are reported. Reactions with CO of the Ni(CO)2(NHC) complexes lead to the quantitative formation of Ni(C

Generation of a Ni3Phosphinidene Cluster from the Ni(0) Synthon, Ni(η3-CPh3)2

Reaction of NiCl2 in THF with 2 equiv of Li(CPh3) at -25 °C results in formation of Ni(η3-CPh3)2 (1) in moderate yield. Complex 1 was fully characterized, which included analysis by X-ray crystallography. In the solid state, 1 features an η3 binding mode

Highly selective catalytic hydroconversion of benzyloxybenzene to bicyclic cyclanes over bifunctional nickel catalysts

An active bifunctional nickel catalyst was prepared by decomposing Ni(CO)4 to highly dispersed metallic Ni onto Hβ zeolite and first applied in hydroconverting benzyloxybenzene (BOB), which was used as a lignin-related model compound. Ni/Hβ proved to be effective for converting BOB to bicyclic cyclanes (BCCs) via Calk–O bond cleavage induced by H+ addition, benzylium addition to 2- and 4-positions in phenol, hydrogenation of benzene ring, dehydration, and H? abstraction. Compared to one-step conversion, the total BCC selectivity (TBCCS) significantly increases from catalytic hydroconversion of catalytically converted BOB by pretreatment under pressurized N2.

Carbon–Fluorine Reductive Elimination from Nickel(III) Complexes

We report a C?F reductive elimination from a characterized first-row aryl metal fluoride complex. Reductive elimination from the presented nickel(III) complexes is faster than C?F bond formation from any other characterized aryl metal fluoride complex.

Molecular nickel poly-carbide carbonyl nanoclusters: The octa-carbide [HNi42C8(CO)44(CuCl)]7- and the deca-carbide [Ni45C10(CO)46]6-

The reaction of [Ni10(C2) (CO)16]2- with CuCl in thf affords [Ni45C10(CO)46]6- as the major product. This represents the first deca-carbide carbonyl cluster and this i

A highly active Ni/ZSM-5 catalyst for complete hydrogenation of polymethylbenzenes

Amazing the crowd: A highly dispersive supported nickel catalyst is prepared by in situ decomposition of Ni(CO)4 over ZSM-5 zeolite. The catalyst displays an amazing activity for complete hydrogenation of polymethylbenzenes which are extremely

Nickel(0) complexes of polyunsaturated azamacrocyclic ligands

A series of nickel(0) complexes, 3, 4, and 5, containing unsaturated 15-membered azamacrocyclic ligands have been synthesized. Structural characterization of the complexes is based on NMR spectroscopy, X-ray diffraction analysis, and differential scanning calorimetry. In addition, the catalytic activity of the complexes in the Suzuki-Miyaura cross-coupling of arylboronic acids and aryl halides has been tested.

Bimetallic nickel-cobalt hexacarbido carbonyl clusters [H 6-nNi22Co6C6(CO)36] n- (n = 3-6) possessing polyhydride nature and their base-induced degradation to the monoacetylide [Ni9CoC2(CO) 16- x]3- (x = 0, 1)

The reaction of [Ni10C2(CO)16] 2- with Co3(μ3-CCl)(CO)9 results in the new bimetallic Ni-Co hexacarbido carbonyl clusters [H 6-nNi22Co6C6(CO)36] n- (n = 3-6), which possess polyhydride nature and can be interconverted by means of acid-base reactions. The tetra-anion [H 2Ni22Co6C6(CO)36] 4- and the hexa-anion [Ni22Co6C 6(CO)36]6- have been isolated in a crystalline state and structurally characterized via X-ray crystallography. The six carbide atoms are lodged into Ni7CoC square antiprismatic cages. Addition of strong bases to [Ni22Co6C6(CO) 36]6- affords mixtures of the monoacetylides [Ni 9CoC2(CO)16]3- and [Ni 9CoC2(CO)15]3-, which have been cocrystallized as [NEt4]3[Ni9CoC 2(CO)16-x] (x = 0.58-0.84) salts, displaying tightly bonded interstitial C2 units.

Intramolecular rearrangement of the imine-amide ligand within the nickel coordination sphere affected by carbon monoxide

The interactions of the nickel imine-amide allyl complex 1 with carbon monoxide and unsaturated hydrocarbons have been studied. It is shown that this complex reacts readily with carbon monoxide to form the nickel(0) diimine carbonyl complex [(2-(1-propenyl)-[1,10]phenanthroline)Ni(CO)2] 2. During the process the ligand undergoes a deep transformation within the nickel coordination sphere. Specifically, the nickel-nitrogen σ-bond turns to an N-donor bond with aromatization of a ring in the nitrogen-containing ligand. This novel heteroaromatic ligand 2-(1-propenyl)-[1,10]phenanthroline has been isolated; the nickel(0) diimine carbonyl complex 2 has been studied with X-ray diffraction method. The comparative spectral studies of complexes 1, 2, and 2-(1-propenyl)-[1,10]phenanthroline have been carried out with UV/vis, IR-FT, and 2D NMR spectroscopy. It has been shown that the planar 16-electron nickel(II) imine-amide allyl complex 1 is indifferent to olefins and acetylenes. Based on the NMR data, this fact can be explained by the inability of the π-δ rearrangement into 1.

A dinuclear nickel complex modeling of the Nid(ii)-Ni p(i) state of the active site of acetyl CoA synthase

The dinuclear Ni(ii)-Ni(i) complex NiII(dadtEt) NiI(SDmp)(PPh3) was synthesized as a Ni(ii) d-Ni(i)p model of the A-cluster in acetyl CoA synthase. This complex was reacted with Co(dmgBFsu