71617-05-5Relevant articles and documents
Thermal Decomposition of Some Dioxastibolanes
Zaburdyaeva, S. N.,Fedorov, A. Yu.,Dodonov, V. A.
, p. 721 - 723 (2008/10/08)
Thermal decomposition of λ**5-dioxastibolanes Ph3SbO2R obtained from triphenylantimony and primary, secondary, and tertiary 1,2-diols is accompanied by cleavage of the endocyclic C-C bond, oxidation of the aliphatic moiety, and liberation of triphenylantimony. When the group R contains a hydrogen atom at the α-carbon atom, decomposition of the organometallic compound involves the triphenylantimony fragment, the C-C bond being retained.