716320-24-0

Upstream product

• 498555-14-9 Carbonic acid ethyl ester 1-[(4R,5S)-5-((4R,5R)-5-hydroxy-2,2-dimethyl-[1,3]dioxan-4-yl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-prop-2-ynyl ester 
• 474103-74-7 Carbonic acid ethyl ester (3aR,4S,5aS,9aR,9bS)-2,2,8,8-tetramethyl-5-methylene-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-yl ester 
• 498555-13-8 (4R,5R)-4-[(4R,5R)-5-(1-Hydroxy-prop-2-ynyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-2,2-dimethyl-[1,3]dioxan-5-ol 
• 474103-76-9 (3aR,4S,5aS,9aR,9bS)-2,2,8,8-Tetramethyl-5-methylene-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxin-4-ol 
• 474103-98-5 (3aR,4S,5aS,9aR,9bS)-4-Benzyloxy-2,2,8,8-tetramethyl-5-methylene-hexahydro-[1,3]dioxolo[4',5':3,4]benzo[1,2-d][1,3]dioxine 
• 357604-61-6 2,3:4,6-di-O-isopropylidene-D-mannopyranose 
• 100-39-0 benzyl bromide 

Downstream Products

• 716320-25-1 (3aS,4R,5S,7S,7aR)-7-Benzyloxy-5-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-6-methylene-hexahydro-benzo[1,3]dioxol-4-ol 
• 716320-26-2 ((3aS,5S,7S,7aS)-7-Benzyloxy-2,2-dimethyl-6-methylene-hexahydro-benzo[1,3]dioxol-5-ylmethoxy)-tert-butyl-diphenyl-silane 
• 716320-27-3 (3aS,4S,5R,6R,7aS)-4-Benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-5-ol 

Relevant academic research and scientific papers

A stereodivergent approach to 5a-carba-α-D-gluco-, -α-D-galacto and -β-L-gulopyranose pentaacetates from D-mannose, based on 6-exo-dig radical cyclization and Barton-Mccombie radical deoxygenation

The three carbasugars, 5a-carba-α-D-gluco-, -α-D-galacto and -β-L-gulopyranose pentaacetates 42, 35 and 28 respectively, have been prepared in a stereodivergent manner from D-mannose. Alkynyl derivatives of 2,3:4,6-di-O-isopropylidene-D-mannopyranose, whi

A general stereodivergent strategy for the preparation of carbasugars. Syntheses of 5a-carba-α-D-glucose, α-D-galactose, and β-L-gulose pentaacetates from D-mannose

A stereodivergent approach to 5a-carba-D- and L-pyranoses has been applied to the preparation of 5a-carba-α-D-gluco-, 5a-carba-α-D-galacto-, and 5a-carba-β-L-gulopyranose pentaacetates. The strategy, by which a single precursor can be transformed into thr