717124-11-3Relevant academic research and scientific papers
Syntheses and anti-HIV and human cluster of differentiation 4 (CD4) down-modulating potencies of pyridine-fused cyclotriazadisulfonamide (CADA) compounds
Lumangtad, Liezel A.,Claeys, Elisa,Hamal, Sunil,Intasiri, Amarawan,Basrai, Courtney,Yen-Pon, Expedite,Beenfeldt, Davison,Vermeire, Kurt,Bell, Thomas W.
, (2020/11/20)
CADA compounds selectively down-modulate human cell-surface CD4 protein and are of interest as HIV entry inhibitors and as drugs for asthma, rheumatoid arthritis, diabetes and some cancers. Postulating that fusing a pyridine ring bearing hydrophobic subst
A formal anti-Markovnikov hydroalkoxylation of allylic alcohols with a ruthenium catalyst
Nakamura, Yushi,Ohta, Tetsuo,Oe, Yohei
, p. 288 - 291 (2018/02/14)
Hydroalkoxylation of C-C double bonds was achieved through the use of a ruthenium catalyst. The reaction of allylic alcohols with nucleophilic alcohols was carried out in the presence of a ruthenium catalyst prepared by RuClH(CO)(PPh3)3 and 2,6-bis(n-butyliminomethyl)-4-(piperidin-1-yl)pyridine under mild reaction conditions to afford the corresponding γ-alkoxypropanols in good yield.
Gated electron sharing within dynamic naphthalene diimide-based oligorotaxanes
Avestro, Alyssa-Jennifer,Gardner, Daniel M.,Vermeulen, Nicolaas A.,Wilson, Eleanor A.,Schneebeli, Severin T.,Whalley, Adam C.,Belowich, Matthew E.,Carmieli, Raanan,Wasielewski, Michael R.,Stoddart, J. Fraser
supporting information, p. 4442 - 4449 (2014/05/06)
The controlled self-assembly of well-defined and spatially ordered π-systems has attracted considerable interest because of their potential applications in organic electronics. An important contemporary pursuit relates to the investigation of charge transport across noncovalently coupled components in a stepwise fashion. Dynamic oligorotaxanes, prepared by template-directed methods, provide a scaffold for directing the construction of monodisperse one-dimensional assemblies in which the functional units communicate electronically through-space by way of π-orbital interactions. Reported herein is a series of oligorotaxanes containing one, two, three and four naphthalene diimide (NDI) redox-active units, which have been shown by cyclic voltammetry, and by EPR and ENDOR spectroscopies, to share electrons across the NDI stacks. Thermally driven motions between the neighboring NDI units in the oligorotaxanes influence the passage of electrons through the NDI stacks in a manner reminiscent of the conformationally gated charge transfer observed in DNA. Birds of a feather flock together: Mutually π-stacked small-molecule naphthalene diimide (NDI) [24]crown-8 derivatives self-assemble dynamically on a repeating -(CH2CH2NH2+CH 2)-template to afford the stepwise evolution of discrete-length oligorotaxanes, which are shown to communicate electronically through their co-facially interacting π-surfaces, sharing electrons across linear arrays containing one, two, three, and four NDI units as determined by cyclic voltammetry and EPR/ENDOR spectroscopies.
