71747-37-0

Basic information

• Product Name: Benzenepropanol, a-ethyl-, (S)-
• Synonyms: (S)-1-phenyl-3-pentanol;Benzenepropanol, α-ethyl-, (S)-;(3S)-1-phenylpentan-3-ol;(S)-1-phenylpentan-3-ol;(S)-(+)-1-phenylpentan-3-ol;(S)-(+)-1-phenyl-3-pentanol;(+)-(S)-1-phenylpentan-3-ol
• CAS NO: 71747-37-0
• Molecular Formula: C11H16O
• Molecular Weight: 164.247
• Mol File: 71747-37-0.mol
• Article Data: 126

Chemical Properties

• Melting Point: 38°C
• Boiling Point: 251.73°C (rough estimate)
• Density: 0.9687
• Refractive Index: 1.5000 (estimate)
• CAS DataBase Reference: Benzenepropanol, a-ethyl-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanol, a-ethyl-, (S)-(71747-37-0)
• EPA Substance Registry System: Benzenepropanol, a-ethyl-, (S)-(71747-37-0)

Safety Data

• Hazardous Substances Data: 71747-37-0(Hazardous Substances Data)

Upstream product

• 71772-85-5 (2S,4S)-2-Phenyltetrahydrothiopyran-4-ol 
• 27975-78-6 1-phenyl-1-pentyn-3-ol 
• 20795-51-1 1-phenylpentan-3-one 
• 557-20-0 diethylzinc 
• 14604-31-0 (E)-1-phenylpent-1-en-4-yn-3-ol 
• 30608-62-9 (S)-(-)-1,2-epoxybutane 
• 6921-34-2 benzylmagnesium chloride 
• 1313022-82-0 (R)-(3-(benzyloxy)pent-4-en-1-yl)benzene 
• 40339-21-7 penta-3,4-dienyl-benzene 
• 1589-82-8 phenylmagnesium bromide 
• 153475-15-1 (R)-1-chloro-4-phenylbutan-2-ol 
• 614-20-0 3-oxo-3-phenylpropionic acid 
• 1352127-75-3 4,4,5,5-tetramethyl-2-(1-phenylpentan-3-yl)-1,3,2-dioxaborolane 
• 104-55-2 3-phenyl-propenal 

Downstream Products

• 1053608-70-0 (3R,4R,5S)-4-Acetylamino-5-azido-3-((S)-1-ethyl-3-phenyl-propoxy)-cyclohex-1-enecarboxylic acid ethyl ester 

Relevant articles and documents

Palladium-Catalyzed Asymmetric Decarboxylative Addition of β-Keto Acids to Heteroatom-Substituted Allenes

The Pd-catalyzed asymmetric addition reaction of β-keto acids to heteroatom-substituted allene is reported. This reaction generates β-substituted ketones in an asymmetric manner through a branch-selective decarboxylative allylation pathway. The reaction accommodates various alkoxyallenes as well as amidoallenes.

Enantioselective addition of diethylzinc to aldehydes catalyzed by 5-cis-substituted proline derivatives

5-Cis-substituted prolinols, prolinamines, and prolinamine sulfonamides proved to be efficient ligands for the enantioselective addition of diethylzinc to aldehydes, providing up to 99% ee. The sense of asymmetric induction can be controlled by the nature

Chiral Lithium Amido Zincates for Enantioselective 1,2-Additions: Auto-assembling Reagents Involving a Fully Recyclable Ligand

A methodology consisting in carrying out enantioselective nucleophilic 1,2-additions (ee values up to 97 %) from cheap, easily accessible, and never described before, chiral lithium amido zincates is presented. These multicomponent reactants auto-assemble when mixing, in a 1:1 ratio, a homoleptic diorganozinc (R2Zn) with a chiral lithium amide (CLA). The latter, obtained after a single reductive amination, plays the role of the chiral inductor and is fully recoverable thanks to a simple acid–base wash, allowing being recycled and re-use without loss of stereochemical information.