71847-25-1Relevant academic research and scientific papers
Copper-Catalyzed (Di)Arylmethylation of Phosphorylamides Under Oxidative Conditions
Zhao, Zijian,Liu, Xiaobo,Hou, Anguo,Lian, Yan
, p. 6857 - 6866 (2019/01/04)
A compatible and practical (di)arylmethylation of phosphorylamides was successfully accessed in the presence of copper iodide as the catalyst, azodiisobutyronitrile as the radical initiator, and di-tert-butyl peroxide as the oxidant. Both methylarenes and diaryl methanes were compatible under the oxidative conditions, enjoying broad functional groups tolerance (51 examples) and good efficiency (up to 90 % yields).
Cobalt-catalyzed oxidative arylmethylation of phosphorylamides
Xiao, Jing,Li, Ping,Zhang, Yingjun,Xie, Dexun,Peng, Zhihong,An, Delie,Dong, Wanrong
, p. 4558 - 4568 (2018/07/30)
A cobalt-catalyzed strategy for N-arylmethylation of phosphorylamides was herein achieved with the assistance of azodiisobutyronitrile as the radical initiator and di-tert-butyl peroxide as the oxidant. Both methylarenes and diaryl methanes were compatible under the oxidative conditions, expressing broad substrate scope (51 examples) and high efficiency (up to 87% yield).
Tertiary α-diarylmethylamines derived from diarylketimines and organomagnesium reagents
Desmarchelier, Alaric,Ortiz, Pablo,Harutyunyan, Syuzanna R.
, p. 703 - 706 (2015/01/09)
Organomagnesium reagents enable swift and versatile derivatisation of diarylimines to the corresponding α-substituted diarylmethylamines in excellent yields, through fast and clean reactions. Where it occurs, 1,2-reduction can be circumvented using readily accessible dialkylmagnesium reagents. This journal is
Synthesis and structural studies of dimeric sodium compounds having pentametallacyclooctane and hexametallacyclo undecane structure using different phosphinamine derivatives
Kottalanka, Ravi K.,Naktode, Kishor,Panda, Tarun K.
, p. 188 - 195 (2013/04/10)
The treatment of two bulky phosphinamines [Ph2PNH(CHPh 2)] (1) and [Ph2PNH(CPh3)] (2) with 30% hydrogen peroxide afforded phosphinicamides [Ph2P(O)NH(CHPh 2)] (3) and [Ph2P(O)NHC
Rh-N-heterocyclic carbene (NHC) complex-catalyzed addition of phenylboronie acid to N-sulfonyl and N-phosphinoyl aldimines
Md., Abu Bakar,Suzuki, Yumiko,Sato, Masayuki
experimental part, p. 973 - 976 (2009/07/18)
Rh-N-heterocyclic carbene (NHC) complexes were generated in situ from imidazolium salts, [RhCl(cod)]2 and t-BuOK in dioxane. In the presence of a catalytic amount of Rh-NHC complexes, the addition reaction of phenylboronic acid to N-sulfonylarylimines and N-phosphinyolarylimines gave the corresponding amines in high yields.
Nickel-catalysed addition of dialkylzinc reagents to N-phosphinoyl- and N-sulfonylimines
Almansa, Raquel,Guijarro, David,Yus, Miguel
, p. 1167 - 1174 (2007/10/03)
A catalytic amount of a nickel complex (0.1-5.3 mol %) extraordinarily increases the reaction rate of the addition of dialkylzinc reagents to N-(diphenylphosphinoyl)- or N-(benzenesulfonyl)imines. The reaction of imines derived from both aromatic and alip
