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Usage

Uses

1. Used in Chemical Research:
1-(Methoxymethyl)-1H-Benzotriazole is used as a model compound in the study of photoelectron spectra of benzotriazoles. This application helps researchers understand the chemical reactivity and behavior of benzotriazoles, which can be crucial for developing new compounds and materials.
2. Used in Material Science:
In the field of material science, 1-(Methoxymethyl)-1H-Benzotriazole is used to prepare a rhenium(IV) complex named [HMEBTA]2[ReIVBr6]. This complex exhibits magnetic properties, making it a valuable compound for further research and potential applications in areas such as data storage and magnetic materials.
Different applications in different industries may include:
Used in Pharmaceutical Industry:
1-(Methoxymethyl)-1H-Benzotriazole could potentially be used as a starting material or intermediate in the synthesis of pharmaceutical compounds, given its unique chemical structure and reactivity.
Used in Chemical Synthesis:
In the chemical synthesis industry, 1-(Methoxymethyl)-1H-Benzotriazole may be utilized as a building block or reactant in the production of various organic compounds, taking advantage of its specific functional groups and properties.

InChI:InChI=1/C8H9N3O/c1-12-6-11-8-5-3-2-4-7(8)9-10-11/h2-5H,6H2,1H3

Upstream product

• 95-14-7 1,2,3-Benzotriazole 
• 109-87-5 Dimethoxymethane 
• 54187-96-1 1-(chloromethyl)-1H-benzotriazole 
• 124-41-4 sodium methylate 
• 67-56-1 methanol 
• 28539-02-8 1-Hydroxymethyl-1H-benzotriazole 

Downstream Products

• 154615-10-8 2-Benzotriazol-1-yl-2-methoxy-1-p-tolyl-ethanone 
• 3524-62-7 benzoin monomethyl ether 
• 4079-52-1 methoxymethyl phenyl ketone 
• 26452-96-0 methyl indane-1-carboxylate 
• 300680-47-1 1-[1-methoxy-2-phenylethenyl]-1H-1,2,3-benzotriazole 
• 251103-74-9 1-benzotriazolyl-1-methoxy-2-phenylpropene 
• 251103-72-7 1-(cyclohexylidene-methoxy-methyl)-1H-benzotriazole 
• 64591-47-5 2-methoxy-1-(4-methylphenyl)ethan-1-one 
• 7624-24-0 1-methoxy-1-phenyl-acetone 
• 24891-74-5 4-phenyl-but-3-enoic acid methyl ester 
• 13351-73-0 1-methyl-1H-benzo[d][1,2,3]triazole 
• 63777-68-4 1-phenethyl-1H-benzo[d][1,2,3]triazole 
• 123622-26-4 N-benzyl-N'-phenethyl-o-phenylenediamine 
• 139225-75-5 2-Benzotriazol-1-yl-2-methoxy-1-phenyl-ethanol 

Relevant academic research and scientific papers

A general synthesis of 1-(1-alkenyl)benzotriazoles

1-Methyl, 1-(alkoxymethyl) and 1-(trimethylsilylmethyl)benzotriazoles are metallated at the α-carbon. Trapping of the resulting metallated species with chlorotrimethylsilane gives compounds which undergo Peterson olefination even with hindered ketones. In some cases, metallation at the 4-position of the benzotriazole is observed. An exhaustive metallation/silylation sequence gives 4-trimethylsilyl substituted 1-benzotriazoles in good yields.

(Benzotriazol-1-yl)methoxymethyl anion: A novel methylal anion equivalent

The title anion readily reacts with a variety of electrophiles to give adducts which, upon treatment with methanol in the presence of p-toluenesulfonic acid, afford the corresponding α-functionalized dimethyl acetals.

Reactions of 1-(α-Alkoxyalkyl)- and 1-(α-(Aryloxy)alkyl)benzotriazoles with the Grignard Reagents. A New and Versatile Method for the Preparation of Ethers

1-(α-Alkoxyalkyl)benzotriazoles deriving from aldehydes (other than formaldehyde), or from ketones, react with Grignard reagents at 110 deg C to provide a high-yielding, general synthesis of dialkyl and aryl ethers.Under similar conditions, 1-(alkoxymethyl)- and 1-((aryloxy)methyl)benzotriazoles give, by a different cleavage pattern of the N-C-O grouping, 1-alkylbenzotriazoles and N,N'-dialkyl-o-phenylenediamines.The 1-(α-alkoxyalkyl)benzotriazoles are easily prepared: (a) by condensation of benzotriazole, an aldehyde, and an alcohol under water-removing conditions; (b) by condensation of a 1-(α-chloroalkyl)benzotriazole with a sodium or potassium alkoxide or aryloxide; and (c) by condensatioon of an acetal or a ketal with benzotriazole.All the 1-(α-alkoxyalkyl)benzotriazoles and dialkyl or alkyl aryl ethers obtained were fully characterized by their 1H and 13C NMR spectra.

The Chemistry of N-Substituted Benzotriazoles. Part 2. Reactions of Benzotriazole with Aldehydes and Aldehyde Derivatives. 1-(α-Hydroxyalky)-, 1-(α-Alkoxyalkyl)-, and 1-(α-Acyloxyalkyl)benzotriazoles

Benzotriazole reacts readily with a variety of aldehydes to yield crystalline 1:1 adducts characterized by strong hydrogen bonding.Corresponding 1-(α-alkoxyalkyl)benzotriazoles are formed in the presence of alcohols, and 1-(α-acetoxyalkyl) analogues resul