71901-91-2Relevant academic research and scientific papers
Synthesis of Silaphenalenes by Ruthenium-Catalyzed Annulation between 1-Naphthylsilanes and Internal Alkynes through C-H Bond Cleavage
Tokoro, Yuichiro,Sugita, Kengo,Fukuzawa, Shin-Ichi
, p. 13229 - 13232 (2015)
Ruthenium-catalyzed annulation of 1-naphthylsilanes with internal alkynes afforded silaphenalenes through cleavage of the C-H bond at the 8-position of the naphthalene. [RuH2(CO){P(p-FC6H4)3}3] efficiently catalyzed the reaction. The use of 1-naphthyldiphenylsilane as a substrate resulted in a better yield of the annulation product compared to the use of silanes with alkyl groups on the silicon atom. Internal alkynes with both aryl and alkyl groups were tolerated in this reaction. Annulation rather than hydrosilylation: A ruthenium catalyst favored annulation products rather than hydrosilylation products in the reaction of 1-naphthylsilanes and alkynes. The annulation proceeded with selective cleavage of the C-H bond at the 8-position of naphthalene. Substrate scope revealed that substituents on the silicon atom played a crucial role and the phenyl group helped to increase the yields.
Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containing various triarylphosphines and their use for arylation of sterically congested aromatic C-H bonds
Ogiwara, Yohei,Miyake, Masashi,Kochi, Takuya,Kakiuchi, Fumitoshi
supporting information, p. 159 - 164 (2017/11/27)
A series of ruthenium complexes, RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3, containing various triarylphosphines were synthesized. Screening of these complexes as catalysts for direct arylation of sterically congested ortho C-H bonds of aromatic ketones improved the yields of the arylation products.
