71910-40-2

Upstream product

• 591-51-5 phenyllithium 
• 851594-67-7 3-(tert-butyldimethylsilanyloxy)-2,2-dimethyl-1-phenylpropan-1-ol 
• 851594-70-2 2-{(2R,6S)-6-[(2R,4R,5S)-7-((2S,6R)-6-Allyl-tetrahydro-pyran-2-yl)-2-(tert-butyl-dimethyl-silanyloxy)-4-hydroxy-5-methyl-heptyl]-tetrahydro-pyran-2-yl}-2-methyl-propionic acid benzyl ester 
• 303-07-1 2,6-Dihydroxybenzoic acid 
• 100-52-7 benzaldehyde 

Downstream Products

• 100-52-7 benzaldehyde 
• 851594-55-3 5-(2-oxopropyl)-2-phenylbenzo[1,3]dioxin-4-one 
• 851594-52-0 5-allyl-2-phenylbenzo[1,3]dioxin-4-one 

Relevant academic research and scientific papers

Synthesis of functionalized salicylate esters and amides by photochemical acylation

(Chemical Equation Presented) Functionalized salicylates in a flash: Photolysis of functionalized benzodioxinones in the presence of alcohols or amines is a powerful method for the synthesis of sterically hindered salicylic esters and amides (see scheme). This reaction tolerates a broad range of functional groups and efficiently engages a wide range of acylation substrates, including sterically hindered nucleophiles that are inert to other acylation methods.