7196-52-3Relevant academic research and scientific papers
Synthesis and characterization of some perfluorophenylphosphine derivatives
Magnelli,Tesi,Lowe Jr.,Mcquistion
, p. 457 - 461 (2008/10/08)
Bis(pentafluorophenyl)chlorophosphine and pentafluorophenyldichlorophosphine are prepared in good yields from pentafluorophenylmagnesium bromide and phosphorus trichloride. The reactions of the halophosphines with the Lewis bases water, ammonia, dimethylamine, and 2-methylaziridine produced substituted phosphines. Oxidative chlorination of bis(pentafluorophenyl)phosphinamide followed by dehydrohalogenation gave perfluorophenylphosphonitriles. The infrared and pertinent proton magnetic resonance spectra of these compounds are discussed.
