71965-15-6

Basic information

• Product Name: titanium(4+) 2-ethoxyethanolate
• Synonyms: titanium(4+) 2-ethoxyethanolate;Titanium(IV)tetrakis(2-ethoxyethanolate)
• CAS NO: 71965-15-6
• Molecular Formula: C₁₆H₃₆O₈Ti
• Molecular Weight: 404.31924
• EINECS: 276-236-5
• Mol File: 71965-15-6.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: titanium(4+) 2-ethoxyethanolate(CAS DataBase Reference)
• NIST Chemistry Reference: titanium(4+) 2-ethoxyethanolate(71965-15-6)
• EPA Substance Registry System: titanium(4+) 2-ethoxyethanolate(71965-15-6)

Safety Data

• Hazardous Substances Data: 71965-15-6(Hazardous Substances Data)

Usage

InChI:InChI=1/4C4H9O2.Ti/c4*1-2-6-4-3-5;/h4*2-4H2,1H3;/q4*-1;

Upstream product

• 110-80-5 2-ethoxy-ethanol 
• 7550-45-0 titanium tetrachloride 
• 546-68-9 titanium(IV) isopropylate 

Downstream Products

• 110-80-5 2-ethoxy-ethanol 

Relevant articles and documents

Alkoxyalkanol and diol modified titanium tetraisopropoxide: Synthesis and characterization of some novel precursors for titania

Titanium complexes of the type [(OPri)4-nTi(OC2H 4OR)n], [(acac)2Ti(O-G-O] and [(acac) 2Ti(OPri)(OCH2CH2SH)] were synthesized from stoichiometric reactions between titanium tetraisopropoxide [(Ti(OPri)4, TPT] and alkoxyalkanols {HOCH2CH 2OR} in 1:1 to 1:4 molar ratios, where R = Et and n-Bu and by the interaction of the precursor [(acac)2Ti(OR)2] with different diols and thiol in 1:1 molar ratio, where G = (CH2) 2, (CH2)5 and C(CH3) 2CH2CH(CH3), R = isoprop. The reactions have been carried out in refluxing benzene under anhydrous conditions to yield mononuclear derivatives. All these compounds were purified by distillation under reduced pressure. On the basis of elemental analysis, IR and NMR (1H and 13C) spectral studies tetrahedral as well as a cis octahedral geometry around Ti(IV) is proposed.