71983-36-3Relevant articles and documents
Anodic Oxidation of Amines. VIII. Oxidation of Ethane-1,2-diamines
Masui, Masaichiro,Kamada, Yoshiyuki,Nishida, Hideko,Ozaki, Shigeko
, p. 940 - 944 (2007/10/02)
Anodic oxidation of ethylenediamines (ethane-1,2-diamines) was investigated by cyclic voltammetry and controlled potential electrolysis in aqueous carbonate buffer (pH 10) at a glassy-carbon electrode.The first wave of the diamines is developed at a lower potential than that of the corresponding β-alkanolamines.Among the oxidative bond cleavages, the relative amount of (α)C-(β)C bond fission is larger than that observed for β-alkanolamines and oxidative deamination is only observed after the (α)C-(β)C bond fission.A scheme for the reaction processes is proposed.Keywords: ethane-1,2-diamine; anodic oxidation; (α)C-(β)C bond fission; C-N bond fission; carbonate buffer; glassy-carbon electrode.