71996-27-5Relevant articles and documents
Formation of 2-phenylselenenylenones and 2-haloenones from enones. Mechanistic and synthetic aspects, X-ray crystal structures of intermediates
Engman, Lars,Toernroos, Karl Wilhelm
, p. 165 - 178 (2007/10/02)
The structure of trans-3-chloro-2-phenylselenenylcyclohexanone (1) was determined by X-ray diffraction.Although this and similar compounds were readily dehydrohalogenated to give vinylic selenides, they were ruled out as intermediates in the synthesis of
SYNTHETIC APPLICATIONS OF 2-PHENYLSELENENYLENONES-III AN OVERVIEW
Liotta, Dennis,Saindane, Manohar,Barnum, Christopher,Zima, George
, p. 4881 - 4890 (2007/10/02)
2-Phenylselenenylenones are versatile species which can be selectively converted a number of different ketones and enones in high overall yields.
Reactions of α-Diazoketones with Phenylselenenyl Chloride. A new Synthesis of α-Chloro- and α-Phenylselenenyl-α,β-unsaturated Ketones
Buckley, Daniel J.,Kulkowit, Sunanta,McKervey, Anthony
, p. 506 - 507 (2007/10/02)
α-Diazoketones react with phenylselenenyl chloride at room temperature giving α-chloro-α-phenylselenenyl ketones; where structural considerations permit these adducts can be transformed via elimination reactions into α-chloro- or α-phenylselenenyl-α,β-uns
