72017-00-6Relevant articles and documents
The direct electrochemical synthesis of phenylselenolato complexes of some main group and late transition elements
Kumar, Rajesh,Tuck, Dennis G.
, p. 127 - 129 (2007/10/02)
The electrochemical oxidation of anodes of selected Main Group or late transition metals (M) in non-aqueous solutions of diphenyl diselenide gives the corresponding M(SePh)n compounds in high yields (M=Zn, Cd, n=2; M=Cu, Ag, Tl, n=1; M=Sn, n=4)
Substitution Reactions of Thallous Thiophenoxide and Thallous Phenylselenide with Halogen-Bearing Substrates
Detty, Michael R.,Wood, Gary P.
, p. 80 - 89 (2007/10/02)
Thallous thiophenoxide (1) and thallous selenide (2) were prepared by the action of either thallous ethoxide or thallous pentoxide on thiophenol and benzeneselenol.The reagents 1 and 2 reacted readily with aroyl and acyl halides, imidoyl chlorides, α-halo ketones, α-halo esters, α-halo lactones, α-halo carboxylic acids, allyl halides, alkyl halides, chlorotrimethylsilane, chloroacetonitrile, and N-chlorosuccinimide to give substitution products and varying amounts of diphenyl disulfide and diphenyl diselenide.The reactions were run as heterogeneous mixtures in ether.The origin of the diphenyl disulfide and diphenyl diselenide was homolytic cleavage of the thallium-sulfur or thallium-selenium bond, on the basis of the products derived from the reactions of N-chlorosuccinimide with 1 and 2.
