38447-68-6

Upstream product

• 618-32-6 Benzoyl bromide 
• 72017-00-6 Thallous Phenyl Selenide 
• 201230-82-2 carbon monoxide 
• 1666-13-3 diphenyl diselenide 
• 143565-02-0 Tellurobenzoic acid Te-(4-fluoro-phenyl) ester 
• 101327-56-4 Se-phenyl(selenothioperoxy)benzoate 
• 98-88-4 benzoyl chloride 
• 5707-04-0 Phenylselenyl chloride 
• 613-94-5 benzoic acid hydrazide 
• 33861-17-5 phenyl trimethylsilyl selenide 
• 93-97-0 benzoic acid anhydride 
• 591-50-4 iodobenzene 
• 41924-21-4 phenyl tributylstannyl selenide 
• 22233-91-6 phenylselenocyclohexane 

Downstream Products

• 20343-90-2 bis(phenylseleno)methane 
• 35050-01-2 α-(phenylseleno)acetophenone 
• 98-86-2 acetophenone 
• 1666-13-3 diphenyl diselenide 
• 93-58-3 benzoic acid methyl ester 
• 128070-79-1 1-[(2R,3R,4R,5S)-3,4-Bis-(tert-butyl-dimethyl-silanyloxy)-5-(2-oxo-2-phenyl-ethyl)-tetrahydro-furan-2-yl]-1H-pyrimidine-2,4-dione 
• 7697-46-3 phenyl(1H-pyrrol-2-yl)methanone 
• 1132-39-4 diphenylselenide 
• 25333-24-8 3-benzoylpropionic acid methyl ester 
• 104307-41-7 4-methoxycarbonyl-6-oxo-6-phenylhexanoic acid methyl ester 
• 119924-82-2 4-Biphenyl-3-yl-4-oxo-butyric acid methyl ester 
• 128070-77-9 C₁₉H₂₀N₂O₆ 
• 62593-89-9 Phenylbenzoyl(tert.butoxy)seleniumchlorid 
• 62593-90-2 Phenylselenchlorid 

Relevant academic research and scientific papers

Synthesis of selenol esters: Palladium-catalyzed coupling of phenyl tributylstannyl selenide with aryl iodides and carbon monoxide

It was found that palladium complex catalyzed three-component coupling of phenyl tributylstannyl selenide with aryl iodides and carbon monoxide to afford the corresponding selenol esters in moderate to good yields.

Photoredox-Enabled Chromium-Catalyzed Alkene Diacylations

Transition-metal-catalyzed cross-coupling reactions are a powerful tool to construct carbon-carbon bonds in modern synthetic chemistry. Chromium catalysis is much less developed compared with the widely used palladium and nickel catalysis. Herein, we repo

Palladium-Catalyzed Carbonylative Synthesis of Aryl Selenoesters Using Formic Acid as an Ex Situ CO Source

A new catalytic protocol for the synthesis of selenoesters from aryl iodides and diaryl diselenides has been developed, where formic acid was employed as an efficient, low-cost, and safe substitute for toxic and gaseous CO. This protocol presents a high functional group tolerance, providing access to a large family of selenoesters in high yields (up to 97%) while operating under mild reaction conditions, and avoids the use of selenol which is difficult to manipulate, easily oxidizes, and has a bad odor. Additionally, this method can be efficiently extended to the synthesis of thioesters with moderate-to-excellent yields, by employing for the first time diorganyl disulfides as precursors.

Synthesis of selenol esters via the reaction of acyl chlorides with diselenides in the presence of Zn dust catalyzed by CoCl2·6H2O

A practical and efficient approach for the synthesis of selenol and thiol esters is described via the reaction of acyl chlorides with diselenides or disulfides in the presence of Zn dust catalyzed by inexpensive CoCl2·6H2O This proto

P-Silylation of Arenes via Organic Photoredox Catalysis: Use of p-Silylated Arenes for Exclusive o-Silylation, o-Acylation, and o-Alkylation Reactions

Photocatalytic regiospecific p-silylation of arenes has been achieved by the coupling of in situ generated silyl radical with arene radical cation. The strategy involves reductive activation of PhSe-SiR3 and single electron transfer from the electron rich

Nickel-Catalyzed Intramolecular Decarbonylative Coupling of Aryl Selenol Esters

This report describes a method for Ni-catalyzed intramolecular decarbonylative coupling, which enables the conversion of areneselenol esters to diaryl selenides. The inexpensive and readily available catalyst can be employed under mild reaction conditions for the construction of structurally diverse diaryl selenides, including heterocyclic and natural product derivatives. (Figure presented.).

Thioesterification and Selenoesterification of Amides via Selective N-C Cleavage at Room Temperature: N-C(O) to S/Se-C(O) Interconversion

The direct nucleophilic addition to amides represents an attractive methodology in organic synthesis that tackles amidic resonance by ground-state destabilization. This approach has been recently accomplished with carbon, nitrogen and oxygen nucleophiles.

Iron(III)-catalyzed synthesis of selenoesters from α-amino carbonyl derivatives at room temperature

An Fe(III)-catalyzed efficient method has been developed for the synthesis of selenoester derivatives in high yields through the coupling of α-amino carbonyl/glycine derivatives and diselenides under ambient air. A library of benzoselenoate derivatives having a variety of substituents has been synthesized. A plausible reaction pathway has been predicted. Experimental results suggest that the reaction proceeds through a radical pathway. Operational simplicity, compatibility with various α-amino carbonyls and diselenides, high yields, fast reaction and mild reaction conditions are the notable advantages of this procedure. We have also shown the practical application of the synthesized selenoesters which is useful to generate peptide bonds in biological sciences.

General, Mild, and Metal-Free Synthesis of Phenyl Selenoesters from Anhydrides and Their Use in Peptide Synthesis

A mild, practical, and simple procedure for phenyl selenoesters synthesis from several anhydrides and diphenyl diselenide was developed. This transition-metal-free method provides a straightforward entry to storable Fmoc-amino acid selenoesters which are effective chemoselective acylating reagents. An application to oligopeptide synthesis was illustrated.

P -Selective (sp2)-C-H functionalization for an acylation/alkylation reaction using organic photoredox catalysis

p-Selective (sp2)-C-H functionalization of electron rich arenes has been achieved for acylation and alkylation reactions, respectively, with acyl/alkylselenides by organic photoredox catalysis involving an interesting mechanistic pathway.