72037-58-2Relevant academic research and scientific papers
Titanium-catalyzed iminohydrazination of alkynes
Banerjee, Sanjukta,Shi, Yanhui,Cao, Changsheng,Odom, Aaron L.
, p. 5066 - 5077 (2007/10/03)
Titanium pyrrolyl complexes Ti(NMe2)2(dap) 2 (1), where dap is 2-(N,N-dimethylaminomethyl)pyrrolyl, and Ti(NMe2)3(bap) (3), where bap is 2,5-bis(N,N- dimethylaminomethyl)pyrrolyl, were found to be eff
Intermolecular alkyne hydroaminations involving 1,1-disubstituted hydrazines
Cao, Changsheng,Shi, Yanhui,Odom, Aaron L.
, p. 2853 - 2856 (2007/10/03)
(figure presented) Two readily prepared catalysts have been developed for the hydroamination of alkynes by 1,1-disubstituted hydrazines. The catalyses are facile with terminal alkynes and some internal alkynes. If the hydrazine bears an aryl group, Fische
Formamidine anions in synthesis. The one-carbon homologation of aldehydes and ketones to nitriles
Santiago,Meyers
, p. 5839 - 5842 (2007/10/02)
Treatment of various carbonyl compounds with the carbanion of the 2-trimethylsilymethyl formamidine 2 gives the enamidine 3 which is readily transformed into the homologated nitriles 6.
