7205-16-5

Basic information

• Product Name: ricid
• Synonyms: ricid
• CAS NO: 7205-16-5
• Molecular Formula: C₉H₁₃O₃PS
• Molecular Weight: 232.236481
• Mol File: 7205-16-5.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 302.5°C at 760 mmHg
• Flash Point: 136.7°C
• Appearance: /
• Density: 1.224g/cm³
• Vapor Pressure: 0.00177mmHg at 25°C
• Refractive Index: 1.532
• CAS DataBase Reference: ricid(CAS DataBase Reference)
• NIST Chemistry Reference: ricid(7205-16-5)
• EPA Substance Registry System: ricid(7205-16-5)

Safety Data

• Hazardous Substances Data: 7205-16-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H13O3PS/c1-11-13(10,12-2)14-8-9-6-4-3-5-7-9/h3-7H,8H2,1-2H3

Upstream product

• 868-85-9 Dimethyl phosphite 
• 100-51-6 benzyl alcohol 
• 6313-36-6 benzyl thiosulphate 
• 100-53-8 phenylmethanethiol 
• 96-36-6 methyl phosphite 
• 121-45-9 phosphorous acid trimethyl ester 
• 14204-26-3 N-(benzylthio)phthalimide 
• 14204-23-0 N-(benzylthio)succinimide 
• 150-60-7 dibenzyl disulphide 
• 6493-73-8 dibenzyltrisulfide 

Relevant articles and documents

Synthetic method for benzyl thiophosphate

The invention provides a synthetic method for benzyl thiophosphate. The method comprises the step of carrying out a stirring reaction for 6-24 hours on benzyl alcohol which is cheap and easily available, wide in source and stable and low in toxicity as an alkylation reagent and sulfur powder and phosphite ester to prepare a benzyl thiophosphate compound in one step at 70-100 DEG C without a catalyst. The method is simple in reaction condition, the raw materials are easily available, excessive alkali is not used, a solvent is not needed, and the method is easy to operate with only one reaction.The method can be also used for amplifying and gram-grade preparation of products conveniently, and has certain research and industrial application prospects.

NHC-Catalyzed Metathesis and Phosphorylation Reactions of Disulfides: Development and Mechanistic Insights

The development of efficient methods for the metathesis and phosphorylation reactions of disulfide compounds is of widespread interest due to their important synthetic utility in polymer, biological, medicinal and agricultural chemistry. Herein, we demonstrate the use of N-heterocyclic carbenes (NHCs) as versatile organocatalysts to promote these challenging reactions under mild conditions. This metal- and oxidant-free protocol is operationally simple with very short reaction times. The interplay between the nucleophilicity and basicity of NHCs in these reactions were also elucidated by NMR studies and high-level ab initio calculations.

Phosphorothioate synthesis based on the redox reaction of phosphite with tellurium(IV) chloride

Phosphoric thiol esters are conveniently prepared by the treatment of phosphorous triesters with thiols in the presence of tellurium(IV) chloride in a redox-type reaction.