7206-29-3

Usage

Uses

Used in Chemical Synthesis:
(Z)-6-Dodecene is used as a building block for the synthesis of various organic compounds, leveraging its unique structure and reactivity.
Used in the Lubricant Industry:
(Z)-6-Dodecene is used as a base material for the production of synthetic lubricants, enhancing their performance and providing improved properties over traditional petroleum-based lubricants.
Used in the Plastics Industry:
In the plastics sector, (Z)-6-Dodecene is utilized to produce specific types of plastics, contributing to the development of materials with tailored characteristics for various applications.
Used in the Surfactant Industry:
(Z)-6-Dodecene is employed as a key component in the manufacturing of surfactants, which are essential in a range of products for their ability to reduce surface tension between two liquids, a gas and a liquid, or a liquid and a solid.
Used in Cleaning Products:
(Z)-6-Dodecene is used as a solvent and emulsifier in industrial and household cleaning products, capitalizing on its ability to dissolve and mix with other substances, thus improving the effectiveness of the cleaning agents.

InChI:InChI=1/C12H24/c1-3-5-7-9-11-12-10-8-6-4-2/h11-12H,3-10H2,1-2H3/b12-11-

Upstream product

• 67-56-1 methanol 
• 64-19-7 acetic acid 
• 52956-98-6 (Z)-6-dodecenoic acid 
• 629-05-0 n-octyne 
• 6975-99-1 6-dodecyne 
• 592-76-7 1-Heptene 
• 300-57-2 allylbenzene 
• 145803-14-1 (E)-1,1-dimethyl-2-(3-phenylpropylidene)hydrazine 

Downstream Products

• 72328-16-6 3,5-dipentyl-1,2,4-trioxolan 
• 66-25-1 hexanal 
• 17046-01-4 1-hydroxypentan-2-one 

Relevant academic research and scientific papers

Ligand-Controlled Cobalt-Catalyzed Transfer Hydrogenation of Alkynes: Stereodivergent Synthesis of Z- and E-Alkenes

Herein, we report a novel cobalt-catalyzed stereodivergent transfer hydrogenation of alkynes to Z- and E-alkenes. Effective selectivity control is achieved based on a rational catalyst design. Moreover, this mild system allows for the transfer hydrogenation of alkynes bearing a wide range of functional groups in good yields using catalyst loadings as low as 0.2 mol %. The general applicability of this procedure is highlighted by the synthesis of more than 50 alkenes with good chemo- and stereoselectivity. A preliminary mechanistic study revealed that E-alkene product was generated via sequential alkyne hydrogenation to give Z-alkene intermediate, followed by a Z to E alkene isomerization process.

Libraries for Receptor-Assisted Combinatorial Synthesis (RACS). The olefin metathesis reaction

A library of alkenes is generated using the olefin metathesis reaction, and converted to a set of diols suitable for a receptor assisted combinatorial synthesis (RACS) experiment with borate as a linker.

Selective cyclotrimerization of acetylenes via tantalum-alkyne complexes

Tantalum-alkyne complexes from internal acetylenes and low-valent tantalum (TaCl5 and Zn) in DME and benzene react with terminal diynes in presence of THF and pyridine to give tetrasubstituted benzene derivatives in good to excellent yields.

Reaction of Tantalum-Alkyne Complexes with Hydrazones. Stereoselective Synthesis of (E)-Allylic Hydrazines

Treatment of tantalum-alkyne complexes with dimethylhydrazones by the assistance of Me3Al in a mixed solvent of DME, benzene, and THF at 45 deg C for 16 h gives (E)-allylic hydrazines stereoselectively.

Z/E-Isomerization of Unsaturated Carboxylic Acids during the Kolbe Electrolysis

Z-4-Enoic acids partially isomerize to E-configurated products in the Kolbe electrolysis.The results from methyl and deuterium labelled carboxylic acids 2 and 16 support an isomerization via a reversible ring closure to cyclopropylcarbinyl radicals.The double bonds of Z-N-enoic acids with N>/= 5 fully retain their configuration in the Kolbe electrolysis; for N=6,7 cyclic products are formed to some extent, which is in accord with the reactivity of 5- and 6-alkenyl radicals.