721396-92-5Relevant academic research and scientific papers
Programmed single step self-assembly of a [2 x 2] grid architecture built on metallic centers of different coordination geometries
Petitjean, Anne,Kyritsakas, Nathalie,Lehn, Jean-Marie
, p. 1168 - 1169 (2004)
A novel type of 2 x 2 grid type architecture incorporating two ions of different geometries results from the single step directed self-assembly of a bischelating ligand combining bridged bidentate and tridentate complexation subunits, designed so as to lead to the ion selective and toposelective introduction of two Zn(II) and two Cu(I) cations at well-defined, diagonally located positions of, respectively, octahedral and tetrahedral coordination geometry.
