72178-64-4

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 108-10-1 4-methyl-2-pentanone 
• 714957-46-7 1-hydroxy-1-(4-methoxy-phenyl)-5-methyl-hexan-3-one 

Downstream Products

• 15540-09-7 1-(4-methoxy-phenyl)-5-methyl-hexan-3-one 
• 17844-01-8 2-(4-Oxo-Δ¹-cyclohexenyl)-6-methyl-heptanol-(4) 
• 18229-88-4 2-(4-methoxyphenyl)-6-methylheptan-4-ol 
• 714957-50-3 2-diazo-4-[2-(4-methoxy-phenyl)-ethyl]-6-methyl-heptanoic acid ethyl ester 
• 714957-49-0 4-[2-(4-methoxy-phenyl)-ethyl]-6-methyl-heptanoic acid ethyl ester 
• 714957-48-9 1-(3-iodo-5-methyl-hexyl)-4-methoxy-benzene 

Relevant academic research and scientific papers

Platinum(IV)-Catalyzed Synthesis of Unsymmetrical Polysubstituted Benzenes via Intramolecular Cycloaromatization Reaction

A one-pot synthesis of polysubstituted benzene derivatives was achieved via a platinum(IV)-catalyzed intramolecular cycloaromatization reaction. The reaction proceeds via a tandem skeletal rearrangment, dehydration and double bond isomerization, which proved to be very useful for the syntheses of a range of interesting polyalkyl-substituted benzenes.

Cyclopentane construction by Rh-catalyzed intramolecular C-H insertion: Relative reactivity of a range of catalysts

The preparation and Rh-mediated cyclization of the α-diazoester 1 are outlined, and its utility in determining the elements that contribute to the reactivity of the intermediate Rh-carbenoid is presented. The rate of disappearance of diazo ester 1 catalyz