722-20-3Relevant academic research and scientific papers
Transition-Metal-Free C(sp3)–S Coupling in Water: Synthesis of Benzyl Dithiocarbamates Using Thiuram Disulfides as an Organosulfur Source
Peng, Han-Ying,Dong, Zhi-Bing
, p. 949 - 956 (2018/11/27)
A simple, highly efficient and environmentally benign method for the synthesis of benzyl dithiocarbamates was reported. Without addition of metal catalyst, a series of 34 benzyl dithiocarbamates were obtained in good to excellent yields by treating benzyl halides with tetraalkylthiuram disulfides in water. The protocol allows easy access to C(sp3)–S bond formation, features the advantages of easy performance, environmental friendliness, good to excellent yields, and good functional tolerance, showing potential value for the preparation of some biologically active compounds.
Direct conversion of methylarenes into dithiocarbamates, thioamides and benzyl esters
Guntreddi, Tirumaleswararao,Vanjari, Rajeshwer,Singh, Krishna Nand
, p. 3887 - 3892 (2014/06/09)
A new strategy for the synthesis of a variety of dithiocarbamates and thioamides has been developed employing inexpensive and readily available methylarenes under metal-free and solvent-free conditions. The approach offers a one-pot procedure and has also been extended to the synthesis of a diverse range of benzyl esters.
A one-pot rapid synthesis of dithiocarbamates from alcohols using a polymer supported diethyl dithiocarbamate anion
Bandgar,Sadavarte,Uppalla
, p. 450 - 451 (2007/10/03)
A polymer supported diethyl dithiocarbamate anion reacts with primary and secondary alcohols via their tirfluoracetates giving alkylated diethyl dithiocarbamates in good yields.
