723-19-3

Basic information

• Product Name: trans-1,2-Dimethoxycarbonyl-1-phenylcyclopropane
• CAS NO: 723-19-3
• Molecular Weight: 234.252
• Mol File: 723-19-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: trans-1,2-Dimethoxycarbonyl-1-phenylcyclopropane(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1,2-Dimethoxycarbonyl-1-phenylcyclopropane(723-19-3)
• EPA Substance Registry System: trans-1,2-Dimethoxycarbonyl-1-phenylcyclopropane(723-19-3)

Safety Data

• Hazardous Substances Data: 723-19-3(Hazardous Substances Data)

Upstream product

• 80-63-7 methyl 2-chloroacrylate 
• 101-41-7 benzeneacetic acid methyl ester 
• 292638-85-8 acrylic acid methyl ester 
• 55064-66-9 Methyl phosphoenolpyruvate 
• 7476-66-6 methyl 2-chloro-2-phenylethanoate 
• 22979-35-7 Methyl phenyldiazoacetate 
• 4358-87-6 (RS)-methyl mandelate 
• 1865-29-8 2-phenyl-acrylic acid methyl ester 
• 96-34-4 methyl chloroacetate 
• 83126-68-5 trimethyl phosphonoacetate 
• 67-56-1 methanol 

Downstream Products

• 185683-76-5 (1R,2S)-1-Phenyl-cyclopropane-1,2-dicarboxylic acid 1-methyl ester 

Relevant articles and documents

Palladium-catalyzed cyclopropanation of electron-deficient olefins with aryldiazocarbonyl compounds

A concise and efficient protocol for the preparation of cyclopropanes from various aryldiazocarbonyl compounds and electron-deficient olefins catalyzed by Pd(OAc)2 is reported.

Stereochemistry of 1,3-Eliminative Cyclopropanation

The estereochemistry of 1,3-eliminative cyclopropanation was established in the NaH-catalyzed condensation system involving carbanionic reagents with chlorine and phosphate as the leaving group.It was proved by means of product analysis that the steric co