7242-17-3

Usage

Uses

Used in Polymer and Resin Production:
(Z)-2-Butenedioic acid diphenyl ester is used as a curing agent for enhancing the properties of polyester resins. Its application reason is to improve the resin's hardness, durability, and chemical resistance, making it suitable for various industrial applications.
Used in Cross-linking in Polymer Chemistry:
In polymer chemistry, (Z)-2-Butenedioic acid diphenyl ester is used as a cross-linking agent to create a network of chemical bonds between polymer chains. This application increases the polymer's mechanical strength, thermal stability, and resistance to solvents.
Used in Organic Synthesis:
(Z)-2-Butenedioic acid diphenyl ester is used as a research reagent in organic synthesis, facilitating the development of new chemical compounds and materials.
Used in Polymer Science:
As a research reagent in polymer science, (Z)-2-Butenedioic acid diphenyl ester aids in the study and development of novel polymers with specific properties tailored for various applications in different industries.

InChI:InChI=1/C4H4BrN3O/c5-3-1-7-8(2-3)4(6)9/h1-2H,(H2,6,9)

Upstream product

• 10565-20-5 phenyl dichloroacetate 
• 110-16-7 maleic acid 
• 108-95-2 phenol 
• 38013-07-9 phenyl hydrogen maleate ester 
• 108-31-6 maleic anhydride 

Downstream Products

• 93103-78-7 (1R,2S,3R,4S)-7-Aza-bicyclo[2.2.1]heptane-1,2,3,4-tetracarboxylic acid dimethyl ester diphenyl ester 
• 337309-42-9 cis-1,2,3,4-tetrahydro-5,8-dimethoxynaphthalene-2,3-dicarboxylic acid diphenyl ester 
• 6338-19-8 (E)-but-2-enedioic acid diphenyl ester 
• 97678-45-0 2-Phenylsulfanyl-succinic acid diphenyl ester 
• 113370-50-6 diphenyl r-2-methoxycarbonyl-2,c-5-diphenylpyrrolodine-c-3,c-4-dicarboxylate 
• 113370-50-6 diphenyl 2,c-5-diphenylpyrrolidine-r-2, c-methoxycarbonyl-3,t-4-dicarboxylate 
• 113370-50-6 diphenyl r-2-methoxycarbonyl-2,t-5-diphenylpyrrolodine-t-3,c-4-dicarboxylate 
• 113370-50-6 diphenyl r-2-methoxycarbonyl-2,t-5-diphenylpyrrolodine-t-3,t-4-dicarboxylate 
• 113370-50-6 diphenyl r-2-methoxycarbonyl-2,t-5-diphenylpyrrolodine-c-3,t-4-dicarboxylate 
• 588-59-0 stilbene 

Relevant academic research and scientific papers

The application of N,N′dibromo-N,N′-1,2-ethanediyl bis(P-toluenesulfonamide) as a powerful reagent for conversion of carboxylic acids into esters and amides with triphenylphosphine

In the presence of equivalent amounts of triphenylphenylphosphine and N,N′-dibromo-N,N′-1,2-ethanediylbis(p-toluenesulphonamide) ester and amide compounds can be generated in high yields from the corresponding carboxylic acid and alcohols or amines.

Electro-organic reactions. Part 54: Quinodimethane chemistry; Part 2 - Electrogeneration and reactivity of o-quinodimethanes

The electrochemical generation and characterisation of a variety of o-quinodimethanes (o-QDMs) are described together with the outcome of preparative experiments in which they are key intermediates. The quinodimethanes are conveniently formed, in DMF, by both direct and redox-catalysed electroreduction of 1,2-bis(halomethyl)arenes. Their predominant reaction is polymerisation to poly(o-xylylene) (o-PX) polymers. In the presence of dienophiles the electrogenerated o-QDMs may undergo efficient cycloaddition reaction and distinctions between the possible mechanisms have been attempted on the basis of voltammetric, preparative and stereochemical experiments. Contrary to the precedent of the corresponding methyl ester, diphenyl maleate radical-anion isomerises only slowly to the fumarate radical-anion, yet co-electrolysis of 2,3-bis(bromomethyl)-1,4-dimethoxybenzene and diphenyl maleate or diphenyl fumarate gives exclusively the corresponding trans-adduct. Co-electrolysis of dimethyl maleate with either 1,2-bis(bromomethyl)benzene (more easily reduced) or 2,3-bis(bromomethyl)-1,4-dimethoxybenzene (less easily reduced) gave only o-PX polymer. The results are rationalised in terms of a double nucleophilic substitution mechanism where electron transfer between dienophile radical-anion and dihalide is relatively slow. Where electron transfer from maleate or fumarate radical-anions is likely to be fast o-quinodimethanes are formed by redox-catalysis and they polymerise rather than undergo Diels-Alder reaction. Dimerisation of the dienophile radical-anions, with k2 = 104 to 105 M-1 s-1, does not apparently compete with nucleophilic substitution or, where relevant, electron transfer.

Generation and Reactions of Novel Copper Carbenoids through a Stoichiometric Reaction of Copper Metal with gem-Dichlorides in Dimethyl Sulfoxide

Copper metal and such gem-dichlorides as α,α-dichloro acid esters, 1a-e, diphenyldichloromethane, 2, benzal chloride, 3, 1,1-dichloro-2-butene, 5, and carbon tetrachloride, 6, were found to produce copper carbenoid intermediates via α,α-elimination of dichlorides along with the formation of CuCl2(DMSO)2.Thus, 1 and 2 gave substituted olefins via a carbenoid coupling reaction.From 5 and 6, reaction products via the oxygen abstraction from DMSO were produced together with dimethyl sulfide; 3 and 4 were found to cause both types of reactions.The carbenoid intermediates formed from 1 did not cause cyclopropanation reaction with cyclohexene in contrast to the conventional carbalkoxy carbenoid generated by a decomposition reaction of ethyl diazoacetate.Also the carbenoid coupling reaction was completely inhibited by the addition of triphenylphosphine, which was contrastive to the formation of phosphonium ylide with a carbenoid from ethyl diazoacetate.