72552-76-2

Basic information

• Product Name: Benzenemethanamine, N-octylidene-, N-oxide
• CAS NO: 72552-76-2
• Molecular Formula: C15H23NO
• Molecular Weight: 233.354
• Mol File: 72552-76-2.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N-octylidene-, N-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N-octylidene-, N-oxide(72552-76-2)
• EPA Substance Registry System: Benzenemethanamine, N-octylidene-, N-oxide(72552-76-2)

Safety Data

• Hazardous Substances Data: 72552-76-2(Hazardous Substances Data)

Upstream product

• 111-64-8 n-octanoic acid chloride 
• 29601-98-7 N-benzylhydroxylamine hydrochloride 
• 139633-09-3 N-Benzyl-N-octylhydroxylamine 
• 100-44-7 benzyl chloride 
• 122744-71-2 trans-Dihydro-3-phenyl-5-(phenylmethyl)-6-heptyl-1,2,4,5-trioxazine 
• 122744-71-2 5-Benzyl-6-heptyl-3-phenyl-[1,2,4,5]trioxazinane 
• 917-64-6 methyl magnesium iodide 

Downstream Products

• 122744-75-6 (3R,6S)-5-Benzyl-3,6-diheptyl-[1,2,4,5]trioxazinane 
• 908020-18-8 C₂₄H₃₇NO₃ 
• 100-51-6 benzyl alcohol 
• 139633-07-1 N-Benzyl-N-(1-phenyloctyl)hydroxylamine 
• 3481-15-0 benzyl alcohol-d1 
• 139633-09-3 N-Benzyl-N-octylhydroxylamine 
• 91-01-0 1,1-Diphenylmethanol 
• 122744-75-6 (3S,6S)-5-Benzyl-3,6-diheptyl-[1,2,4,5]trioxazinane 
• 622-42-4 1-nitro-1-phenylmethane 
• 124-13-0 Octanal 
• 3378-36-7 α-Nitrosotoluene dimer 
• 139632-95-4 Dihydro-3-cyclohexyl-5-(phenylmethyl)-6-heptyl-1,2,4,5-trioxazine 
• 150151-36-3 Dihydro-3,6-diheptyl-5-(phenylmethyl)-1,2,4,5-trioxazine 
• 139655-46-2 3-Heptyl-4-benzyl-1,2,5-triox-4-azaspiro<5.5>undecane 

Relevant articles and documents

Reductive approach to nitrones from N-Siloxyamides and N-Hydroxyamides

This article describes the full details of our reductive approach to nitrones from amides. Reduction of N-siloxyamides with the Schwartz reagent [Cp2ZrHCl], followed by addition of an acid provided functionalized nitrones. The developed conditi

An Iridium-Catalyzed Reductive Approach to Nitrones from N-Hydroxyamides

An Ir-catalyzed reductive formation of functionalized nitrones from N-hydroxyamides was reported. The reaction took place through two types of iridium-catalyzed reactions including dehydrosilylation and hydrosilylation. The method showed high chemoselectivity in the presence of sensitive functional groups, such as methyl esters, and was successfully applied to the synthesis of cyclic and macrocyclic nitrones, which are known to be challenging compounds to access by conventional methods. 1H NMR studies strongly supported generation of an N-siloxyamide and an N,O-acetal as the actual intermediates.

Oxidation of N,N-Disubstituted Hydroxylamines to Nitrones with Hypervalent Iodine Reagents

Hypervalent iodine compounds are viable reagents for the oxidation of N,N-disubstituted hydroxylamines to the corresponding nitrones, with IBX performing best. The procedure is very simple and user-friendly and affords the target compounds with high effic