72564-98-8

Upstream product

• 75-09-2 dichloromethane 
• 52492-41-8 2,3,5-Tri-O-benzyl-1-brom-D-arabinofuranose 
• 29877-76-7 4-methoxy-2-methylthio-7H-pyrrolo[2,3-d]pyrimidine 
• 70613-79-5 2,3,5-tri-O-benzyl-D-arabinofuranosyl bromide 

Downstream Products

• 79816-02-7 3,7-Dihydro-2-methylthio-7-(2,3,5-tri-O-benzyl-β-D-arabinofuranosyl)-4H-pyrrolo<2,3-d>pyrimidin-4-on 
• 79816-05-0 4-Amino-3,7-dihydro-3-methoxymethyl-7-(2,3,5-tri-O-benzyl-β-D-arabinofuranosyl)-4H-pyrrolo<2,3-d>pyrimidin-4-on 
• 79816-04-9 2-Acetamido-3,7-dihydro-3-methoxymethyl-7-(2,3,5-tri-O-benzyl-β-D-arabinofuranosyl)-4H-pyrrolo<2,3-d>pyrimidin-4-on 
• 79816-03-8 3,7-Dihydro-3-methoxymethyl-2-methylthio-7-(2,3,5-tri-O-benzyl-β-D-arabinofuranosyl)-4H-pyrrolo<2,3-d>pyrimidin-4-on 

Relevant academic research and scientific papers

4,4'-Dimethoxy-2,2'-bis(methylthio)-7,7'-methylenedi(7H-pyrrolopyrimidine) - Bridging of Aglycons by Phase-Transfer Catalysis in Dichloromethane

During phase-transfer glycosylation of the pyrrolopyrimidine 1a with 2,3,5-tri-O-benzyl-1-bromo-D-arabinofuranose in aqueous NaOH/CH2Cl2 in the presence of molar amounts of tetrabutylammonium hydrogen sulfate a by-product of the aglycon was observed.Using the same conditions, but omitting the halogenose the same substance was obtained and assigned to have the structure 4b.The novel 7,7'-methylenedipyrrolopyrimidine is a suitable model for the study of stacking interactions.