72695-42-2Relevant academic research and scientific papers
Heterocyclic Polyfluoro-compounds. Part 32. Photochemical Reactions of 3-Chlorotetrafluoro- and 3,5-Dichlorotrifluoro-pyridines with Olefins, and their Photoreduction
Barlow, Michael G.,Haszeldine, Robert N.,Langridge, John R.
, p. 2520 - 2522 (2007/10/02)
Ethylene reacts photochemically with 3-chlorotetrafluoropyridine to yield 3-(2-chloroethyl)tetrafluoropyridine, and cyclo-pentene and -hexene yield the corresponding 3-cycloalkyltetrafluoropyridines.Photochemical reaction of cyclohexene with 3,5-dichlorotrifluoropyridine yields 3-chloro-5-cyclohexyltrifluoropyridine.The chlorine in 3-chlorotetrafluoropyridine, and one of the chlorines in 3,5-dichlorotrifluoropyridine, is readily reduced photochemically in solvents such as ethanol, diethyl ether, or acetone.
