72843-32-4

Upstream product

• 106035-79-4 (R)-3-(4-methylphenyl)-1-butanol 
• 192512-75-7 Methanesulfonic acid (S)-2-p-tolyl-propyl ester 
• 192512-81-5 (R)-3-(4-methylphenyl)butanenitrile 
• 93922-51-1 (S)-2-(4-methylphenyl)-1-propanol 
• 104598-15-4 (R)-3-(4-methylphenyl)butanal 
• 131605-39-5 (R)-3-hydroxy-2-(4-methylphenyl)propyl acetate 
• 4424-32-2 2-(4-methylphenyl)-1,3-propanediol 

Downstream Products

• 192766-60-2 Trimethyl-((R)-5-p-tolyl-hex-1-ynyl)-silane 
• 101693-57-6 (R)-(+)-4-methyl-4-(4-methylphenyl)cyclopent-2-enone 
• 192513-08-9 1-Methyl-4-((R)-1-methyl-cyclopent-2-enyl)-benzene 
• 192513-04-5 1-((R)-3-Benzenesulfonyl-1-methyl-cyclopent-2-enyl)-4-methyl-benzene 

Relevant academic research and scientific papers

New asymmetric construction of the benzylic quaternary stereogenic centre: An enantiocontrolled access to (-)-α-cuparenone

An efficient and enantiocontrolled formal total synthesis of (-)-α-cuparenone has been accomplished by employing a new asymmetric construction methodology for formation of the benzylic quaternary stereogenic centre.

Asymmetric total synthesis of optically active α-curcumene

(R)-(-)-α-Curcumene has been prepared in 66% optical yield and in 34% overall yield in five steps by means of asymmetric Grignard cross-coupling reaction catalyzed by a nickel complex of chiral (aminoalkylferrocenyl)phosphine as a key carbon-carbon bond forming step.