72886-48-7Relevant academic research and scientific papers
[Mes-B-TMP]+borinium cation initiated cyanosilylation and catalysed hydrosilylation of ketones and aldehydes
Chen, Po-Han,Chiu, Ching-Wen,Hsu, Ching-Pei,Liu, Yi-Hung,Tseng, Hsi-Ching
supporting information, p. 13732 - 13735 (2021/12/27)
Two aryl amino borinium cations derived from Cl(Mes)B-NR2(NR2= TMP, HMDS) faced divergent outcomes. As the HMDS-substituted one underwent methyl migration from silicon to boron transforming the putative borinium ion to a silylium ion, [Mes-B-TMP]+can initiate cyanosilylation and catalyse hydrosilylation of ketones and aldehydes.
