73006-68-5Relevant academic research and scientific papers
Amidoselenation and Amidotelluration of Alkenes using Oxygen as Terminal Oxidant
Sun, Kai,Wang, Xin,Zhang, Chong,Zhang, Saifei,Chen, Yao,Jiao, Hezhen,Du, Weimin
, p. 713 - 717 (2017/03/22)
A protocol has been established for oxygen-mediated amidoselenation and amidotelluration of alkenes under mild conditions. This method provides a simple route to a series of structurally diverse β-amido selenides and β-amido tellurides in moderate to high
Metal-Free Catalytic Approach for Allylic C-H Amination Using N-Heterocycles via sp3 C-H Bond Activation
Sun, Jinwei,Wang, Yi,Pan, Yi
, p. 8945 - 8950 (2015/09/28)
A versatile metal-free synthesis of allylic N-heterocycles has been developed using a TBAI/TBHP oxidation system. This general protocol could be applied for the C-N bond formation of electron-deficient phthalimides, imidazoles, triazoles, and sulfonamides
Facile one-pot synthesis of N-alkylated benzimidazole and benzotriazole from carbonyl compounds
Meng, Xu,Li, Xiaolong,Chen, Wenlin,Zhang, Yuanqing,Wang, Wen,Chen, Jinying,Song, Jinli,Feng, Huijie,Chen, Baohua
, p. 349 - 356 (2014/04/17)
An efficient one-pot N-alkylation of benzimidazole and benzotriazole from carbonyl compounds and tosylhydrazide has been accomplished via copper powder-catalyzed N - H bond insertion affording N-alkylated products in good yields. The reaction can tolerate a wide range of carbonyl compounds, such as aryl, alkyl, heterocyclic and α,β-unsaturated ketones, and aldehydes.
Allylic amination via decarboxylative C-N bond formation
Mellegaard-Waetzig, Shelli R.,Rayabarapu, Dinesh Kumar,Tunge, Jon A.
, p. 2759 - 2762 (2007/10/03)
This manuscript details the development of a palladium-catalyzed allylic amination that proceeds via decarboxylation of allylic carbamates. Both saturated and aromatic heterocycles undergo decarboxylative rearrangement in good yields. The mechanism of allylation of heteroaromatic amines involves the formation of π-allyl palladium complexes followed by decarboxylation of the carbamate. Finally, the heteroaromatic anion equivalent is allylated to provide allylic amines. Georg Thieme Verlag Stuttgart.
