7302-08-1Relevant academic research and scientific papers
CARBON-CARBON BOND FORMATION WITH METALLIC MANGANESE
Hiyama, Tamejiro,Sawahata, Miwa,Obayashi, Michio
, p. 1237 - 1238 (1983)
Metallic manganese is found to reduce allylic bromides and achieve the Barbier-type carbonyl addition of allyl unit.
CaII-Catalyzed Alkenylation of Alcohols with Vinylboronic Acids
Leb?uf, David,Presset, Marc,Michelet, Bastien,Bour, Christophe,Bezzenine-Lafollée, Sophie,Gandon, Vincent
supporting information, p. 11001 - 11005 (2015/11/10)
Direct alkenylation of a variety of alcohols with vinylboronic acids has been accomplished using the air-stable calcium(II) complex Ca(NTf2)2 under mild conditions with short reaction times. For reluctant transformations, an ammonium salt was used as an additive to circumvent the reactivity issue. Cross-coupling: Direct alkenylation of a variety of alcohols with vinylboronic acids has been accomplished using the air-stable calcium(II) complex Ca(NTf2)2 under mild conditions with short reaction times (see scheme)
