7305-10-4

Upstream product

• 150-76-5 4-methoxy-phenol 
• 79-44-7 N,N-Dimethylcarbamoyl chloride 
• 10345-49-0 O-(4-methoxyphenyl) N,N-dimethylcarbamothioate 

Downstream Products

• 613-37-6 4-methoxylbiphenyl 
• 1414838-15-5 (E)-ethyl 3-{2-[(N,N-dimethylcarbamoyl)oxy]-5-methoxyphenyl}acrylate 
• 1414838-30-4 (E)-ethyl 3-{2-[(N,N-dimethylcarbamoyl)oxy]-5-(trifluoromethyl)phenyl}acrylate 
• 1452841-56-3 2-benzoyl-4-methoxyphenyl dimethylcarbamate 
• 1631050-33-3 2-hydroxy-4-methoxyphenyl dimethylcarbamate 
• 5683-33-0 2-(Dimethylamino)pyridine 
• 5957-90-4 4-(2-pyridinyl)anisole 
• 62291-63-8 p-methoxyphenyl propyl sulfide 
• 2620-82-8 1-methyl-2-(4-methoxyphenyl)-1H-benzimidazole 
• 1401518-49-7 2-(4'-methoxy-4-methyl-[1,1'-biphenyl]-2-yl)-5-methylpyridine 
• 1401518-62-4 2-(4-methoxyphenyl)-3-methyl-1-(pyridin-2-yl)-1H-indole 
• 1310709-07-9 2-(4-methoxyphenyl)-1-(pyridin-2-yl)-1H-indole 
• 1251668-23-1 2-(6-fluoro-4'-methoxy-[1,1'-biphenyl]-2-yl)pyridine 
• 213596-33-9 2-(4-methoxyphenyl)-5,5-dimethyl-1,3,2-dioxaborolane 

Relevant academic research and scientific papers

Iron(II)/Persulfate Mediated Newman-Kwart Rearrangement

Herein, we report that iron(II)/ammonium persulfate in aqueous acetonitrile mediates the Newman-Kwart rearrangement of O-aryl carbamothioates. Electron-rich substrates react rapidly under moderate heating to afford the rearranged products in excellent yie

Inverting the Selectivity of the Newman-Kwart Rearrangement via One Electron Oxidation at Room Temperature

The discovery that the Newman-Kwart rearrangement can be performed at room temperature by action of a simple and readily available oxidant, cerium ammonium nitrate, is described. The conditions give clean conversion when using electron-rich aromatic subst

A general approach towards catechol and pyrogallol through ruthenium- and palladium-catalyzed C-H hydroxylation by weak coordination

An efficient ruthenium(II)- and palladium(II)-catalyzed C-H hydroxylation of aryl carbamates has been developed for the facile synthesis of catechols and pyrogallols. The reaction demonstrates excellent reactivity, regio- and chemoselectivity, good functional group compatibility and high yields. The practicality of this method has been proved by a gram-scale synthesis.

Nickel-catalyzed efficient and practical Suzuki-Miyaura coupling of alkenyl and aryl carbamates with aryl boroxines

(Figure Presented) Suzuki-Miyaura coupling of unactivated alkenyl carbamates Is described to construct polysubstituted olefins. The developed process is also suitable for heteroaromatic and even electron-rich aromatic carbamates.

Infrared Spectra and Transmission of Electronic Effects in Substituted Phenyl N,N-Dimethylcarbamates and S-Phenyl N,N-Dimethylthiocarbamates

Carbonyl stretching frequencies in CCl4 and CHCl3 and hydroxyl stretching frequency shifts of phenol as a proton donor in CCl4 were measured for series of substituted phenyl N,N-dimethylcarbamates (I) and S-phenyl N,N-dimethylthiocarbamates (II).The data